质量水平
检测方案
98%
反应适用性
reagent type: ligand
reaction type: Coupling Reactions
reagent type: ligand
reaction type: Epoxidations
reagent type: ligand
reaction type: Michael Reaction
mp
150-157 °C (lit.)
官能团
phosphine oxide
SMILES字符串
O=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI key
FIQMHBFVRAXMOP-UHFFFAOYSA-N
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应用
高三苯基氧化膦可用于：
- 用作无环伯醇和仲醇的Appel型氯化反应的催化剂。
- 用作α,β-不饱和酸酯和andβ,γ-不饱和酮酯α-化合物在立体选择性聚和二溴化的催化剂。
- 用作启动子，通过乙醇与呋核亚硝脲碘化物的非对映选择性合成α呋喃糖苷
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 3
WGK
WGK 2
闪点(°F)
356.0 °F
闪点(°C)
180 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
?-Selective Ribofuranosylation of Alcohols with Ribofuranosyl Iodides and Triphenylphosphine Oxide
Oka N, et al.
The Journal of Organic Chemistry, 79(16), 7656-7664 (2014)
Triphenylphosphine oxide-catalyzed stereoselective poly-and dibromination of unsaturated compounds
Yu T, et al.
Chemical Communications (Cambridge, England), 50(58), 7817-7820 (2014)
Phosphine oxide-catalysed chlorination reactions of alcohols under Appel conditions
Denton RM, et al.
Chemical Communications (Cambridge, England), 46(17), 3025-3027 (2010)
R Kyle Palmer et al.
Assay and drug development technologies, 8(6), 703-713 (2010-12-17)
Transient receptor potential melastatin-5 (TRPM5) is a calcium-gated monovalent cation channel expressed in highly specialized cells of the taste bud and gastrointestinal tract, as well as in pancreatic β-cells. Well established as a critical signaling protein for G protein-coupled receptor-mediated
Steven Kealey et al.
Dalton transactions (Cambridge, England : 2003), (42)(42), 4763-4765 (2007-10-24)
A new tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide moieties appended to the 3-position of the pyrazolyl rings is reported and shown to display varied coordination chemistry from tridentate N(2)O coordination with thallium to hexadentate N(3)O(3) coordination with europium.
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