质量水平
检测方案
97%
bp
230-235 °C/20 mmHg (lit.)
mp
109-112 °C (lit.)
SMILES字符串
ClC(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI key
JBWKIWSBJXDJDT-UHFFFAOYSA-N
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应用
三苯甲基氯可用作以下应有的催化剂:
- Ritter型合成,通过萘酚,芳基醛和乙腈进行一锅三组分反应,合成1-氨基烷基-2-萘酚。
- 通过偶苯酰与醛、伯胺以及乙酸铵进行一锅多组分反应,合成1,2,4,5-四取代咪唑。
- 在无溶剂条件下通过酚、芳香醛和酰胺进行一锅多组分反应制备酰胺烷基酚。
- 通过芳香醛、胺和β-酮酯进行一锅多组分反应合成取代哌啶。
胺、醇和硫醇的保护剂。
警示用语:
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Trityl chloride as an efficient organic catalyst for the synthesis of 1-amidoalkyl-2-naphtols in neutral media at room temperature
Applied Catalysis A: General, 386(1-2), 179-187 (2010)
Trityl chloride as an efficient organic catalyst for one-pot, five-component and diastereoselective synthesis of highly substituted piperidines
Research on Chemical Intermediates, 40(2), 723-736 (2014)
Tetrahedron Letters, 48, 5017-5017 (2007)
One pot synthesis of 1, 2, 4, 5-tetrasubstituted-imidazoles catalyzed by trityl chloride in neutral media
Royal Society of Chemistry Advances, 4(105), 60636-60639 (2014)
Biochimica et biophysica acta, 847(1), 1-7 (1985-10-30)
Intercellular junctional communication was measured using [14C]citrulline incorporation in co-cultures of argininosuccinate synthetase-deficient and argininosuccinate lyase-deficient human fibroblasts. Triphenylmethane, triphenylmethylchloride and tetraphenylboron inhibited communication at concentrations at least 12-fold lower than cytotoxic concentrations. This inhibition was of rapid onset and
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