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Merck
CN
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文件

T7394

Sigma-Aldrich

N,N,N′,N′-四甲基对苯二胺

99%, powder

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别名:
TMPD, TMPDA, TMPPD, Wurster 试剂
线性分子式:
C6H4[N(CH3)2]2
分子量:
164.25
Beilstein:
1564025
EC 号:
202-831-6
MDL编号:
MFCD00008309
UNSPSC代码:
12352100
PubChem化学物质编号:
57654696
NACRES:
NA.22

质量水平

200

检测方案

99%

形式

flakes
powder

颜色

off-white to brown

bp

260 °C (lit.)

mp

49-51 °C (lit.)

SMILES字符串

CN(C)c1ccc(cc1)N(C)C

InChI

1S/C10H16N2/c1-11(2)9-5-7-10(8-6-9)12(3)4/h5-8H,1-4H3

InChI key

CJAOGUFAAWZWNI-UHFFFAOYSA-N

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相关类别

一般描述

N,N,N′,N′-四甲基对苯二胺(TMPDA)是一种低电离电位的氧化还原试剂，广泛用作光系统I的电子供体。它还可用作光系统II的电子受体。

应用

N,N,N′,N′-四甲基对苯二胺(TMPDA)可用于：
  • 过氧苯甲酰的流动注射分析。
  • 研究其到卤化溶剂的光致电子转移。

注意

储存中颜色可能变深。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H302 + H312 + H332

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

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Flow injection analysis of benzoyl peroxide using N, N, N, N-tetramethyl-p-phenylenediamine (TMPDA) and surfactants
Pharr DY & Tomsyck JA
Analytical Letters, 42(5), 821-832 (2009)
Ultrafast photoinduced electron transfer from N, N, N′ , N′ -tetramethyl-p-phenylenediamine and N, N, N′ , N′ -tetramethylbenzidine to dichloromethane
Boilet L, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 163(3), 529-536 (2004)
Interaction of N, N, N′ ,N′ -tetramethyl-p-phenylenediamine with photosystem II as revealed by thermoluminescence: reduction of the higher oxidation states of the Mn cluster and displacement of plastoquinone from the QB niche
Gauthier A, et al.
Biochimica et Biophysica Acta, 1757(11), 1547-1556 (2006)
Toshiaki Miura
Chemico-biological interactions, 236, 67-73 (2015-04-30)
To investigate the mechanisms of cardiotoxicity induced by adriamycin (ADM), the enzymatic activities of ADM-Fe(3+), including the peroxidase and lipoxygenase (LOX) activity, and participation of active oxygen species in the damage to biological components were examined. ADM-Fe(3+), but not ADM
Youngno Kim et al.
Scientific reports, 10(1), 16488-16488 (2020-10-07)
Stretchable materials are essential for next generation wearable and stretchable electronic devices. Intrinsically stretchable and highly conductive polymers (termed ISHCP) are designed with semi interpenetrating polymer networks (semi-IPN) that enable polymers to be simultaneously applied to transparent electrodes and electrochromic
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