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蒸汽压
<2 mmHg ( 20 °C)
质量水平
方案
95%
折射率
n20/D 1.411 (lit.)
沸点
63-64 °C/11 mmHg (lit.)
密度
0.844 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)OP(OC(C)C)OC(C)C
InChI
1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
InChI key
SJHCUXCOGGKFAI-UHFFFAOYSA-N
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应用
亚磷酸三异丙酯可作为反应剂：
它还可在光延反应中替代三苯基膦，方便产物分离。
- 与钌亚茚基 (ruthenium indenylidene) 复合物形成复分解反应的第一代复合物。
- 在Perkow反应中用于合成含极化碳碳双键的化合物。
- 与芳香胺和亚硝酸异戊酯反应合成膦酰肼。
它还可在光延反应中替代三苯基膦，方便产物分离。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Skin Irrit. 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
154.4 °F - closed cup
闪点(°C)
68 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Ruthenium indenylidene ?1st generation? olefin metathesis catalysts containing triisopropyl phosphite
Guidone S, et al.
Beilstein Journal of Organic Chemistry, 11, 1520-1520 (2015)
Mitsunobu reactions of nucleoside analogs using triisopropyl phosphite-DIAD
Veliz EA and Beal PA
Tetrahedron Letters, 47(18), 3153-3156 (2006)
Convenient synthesis of phosphonohydrazines from arylamines
Kent GT, et al.
Tetrahedron Letters, 57(19), 2097-2099 (2016)
Nef-isocyanide-Perkow synthesis of new polarized olefins containing 2-dicyanomethylene-2, 3-dihydrothiazole and 2-dicyanomethylene-1, 3-dithiole moieties
Yavari I, et al.
Tetrahedron, 69(11), 2462-2467 (2013)
Su Mei Liu et al.
Marine pollution bulletin, 60(9), 1591-1599 (2010-04-30)
Inorganic or bulk organic chemical indicators, including organic carbon (OC), total nitrogen, organic nitrogen (ON), fixed ammonium (N(fix)), exchangeable ammonium, exchangeable nitrate, organic phosphorus (OP), inorganic phosphorus (IP), and biogenic silica (BSi), were examined in a 3-m core collected in
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