T62804
1,1,1-三氟丙酮
97%
别名:
α,α,α-三氟丙酮, 1,1,1-三氟-2-丙酮, 3,3,3-三氟丙酮, 三氟甲基甲酮, 甲基三氟甲基酮
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关于此项目
线性分子式:
CH3COCF3
化学文摘社编号:
分子量:
112.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-005-9
Beilstein/REAXYS Number:
1748614
MDL number:
产品名称
1,1,1-三氟丙酮, 97%
InChI key
FHUDAMLDXFJHJE-UHFFFAOYSA-N
InChI
1S/C3H3F3O/c1-2(7)3(4,5)6/h1H3
SMILES string
CC(=O)C(F)(F)F
vapor pressure
13.62 psi ( 20 °C)
assay
97%
refractive index
n20/D 1.3 (lit.)
bp
22 °C (lit.)
density
1.252 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
用于以 2,6-二卤吡啶为原料合成 2-三氟甲基-7-氮杂吲哚。该手性亚胺衍生物用于通过 Strecker 反应和随后的腈水解或还原反应，制备对映纯 α-三氟甲基丙氨酸和二胺。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-22.0 °F - closed cup
flash_point_c
-30 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Synthesis, 251-251 (2007)
Florent Huguenot et al.
The Journal of organic chemistry, 71(18), 7075-7078 (2006-08-26)
Diastereomerically pure alpha-trifluoromethyl alpha-amino nitriles obtained by Strecker-type reactions from chiral CF3 imines and iminium proved to be very attractive versatile intermediates for the synthesis of various alpha-trifluoromethyl amino compounds. From these synthons, both enantiomers of alpha-trifluoromethyl alanine, trifluoromethyl 1,2-diamines
Emre Kinaci et al.
Polymers, 12(9) (2020-09-20)
In this investigation, the terminal double bonds of the side chain epoxidized cardanol glycidyl ether (SCECGE) molecule were further epoxidized in the presence of Oxone® (potassium peroxomonosulfate) and fluorinated acetone. Regular methods for the double bond epoxidation are not effective
Sheida Esmaielzadeh et al.
Acta chimica Slovenica, 63(2), 351-362 (2016-06-23)
Some cobalt(III) complexes with a potentially tetradentate unsymmetrical NNOS Schiff base ligand have been synthesized and characterized using IR, 1HNMR, UV-Vis spectroscopy and elemental analysis. The equilibrium constants were measured spectrophotometrically for 1:1 adduct formation of the cobalt(III) complexes with
Jobst Liebau et al.
The Journal of biological chemistry, 295(29), 9868-9878 (2020-05-22)
Fold-switch pathways remodel the secondary structure topology of proteins in response to the cellular environment. It is a major challenge to understand the dynamics of these folding processes. Here, we conducted an in-depth analysis of the α-helix-to-β-strand and β-strand-to-α-helix transitions
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