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线性分子式:
[CH3(CH2)3]3SnCl
化学文摘社编号:
分子量:
325.51
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
215-958-7
Beilstein/REAXYS Number:
3535715
MDL number:
产品名称
三丁基氯化锡, 96%
InChI key
GCTFWCDSFPMHHS-UHFFFAOYSA-M
InChI
1S/3C4H9.ClH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1
SMILES string
CCCC[Sn](Cl)(CCCC)CCCC
vapor pressure
<0.01 mmHg ( 20 °C)
assay
96%
refractive index
n20/D 1.492 (lit.)
bp
171-173 °C/25 mmHg (lit.)
density
1.2 g/mL at 25 °C (lit.)
Quality Level
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Application
Tributyltin chloride (Bu3SnCl or tri-n-butylstannane) is an organotin compound that can be used as a reagent for:
- The synthesis of fluorinated stannanes by reacting with fluorinated alkyl, aryl or vinyl halides using Zn or Cd catalyst via Barbier-type reaction.
- The preparation of γ-hydroxyvinylstannanes, and indol-2-yltributylstannane.
- The conversion of organozirconiums to organostannanes.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
226.4 °F - closed cup
flash_point_c
108 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Fluorinated stannanes: Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium
Burton DJ and Jairaj V
Journal of Fluorine Chemistry, 126(5), 797-801 (2005)
Transmetalation from zirconium to tin: A facile preparation of organostannanes from organozirconiums
Kim S and Kim KH
Tetrahedron Letters, 36(21), 3725-3728 (1995)
Rita Jordão et al.
Environmental health perspectives, 123(8), 813-819 (2015-03-25)
The analysis of obesogenic effects in invertebrates is limited by our poor knowledge of the regulatory pathways of lipid metabolism. Recent data from the crustacean Daphnia magna points to three signaling hormonal pathways related to the molting and reproductive cycles
A Route to the Preparation of γ -Hydroxyvinylstannanes
Lautens M and Huboux AH
Tetrahedron Letters, 31(22), 3105-3108 (1990)
Shin-Ichi Kitamura et al.
Marine pollution bulletin, 124(2), 835-838 (2017-02-23)
We investigated the effect of combined exposure to nodavirus infection and TBT on medaka (Oryzias latipes). Medaka larvae were infected by immersion in medium containing nodavirus at titers of 10
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