产品名称
三烯丙基胺, 99%
InChI key
VPYJNCGUESNPMV-UHFFFAOYSA-N
InChI
1S/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2
SMILES string
C=CCN(CC=C)CC=C
vapor density
4.73 (vs air)
vapor pressure
90 mmHg ( 80 °C)
assay
99%
refractive index
n20/D 1.451 (lit.)
bp
150-151 °C (lit.)
density
0.79 g/mL at 25 °C (lit.)
Quality Level
Application
- 在钌催化剂的存在下，三烯丙基胺（TAA）可与伯芳族胺反应形成2-乙基-3-甲基喹啉。
- TAA通过加氢锆化反应，然后用四氯化锗进行金属转移，形成1-氮杂-5-锗-5-氯双环[3.3.3]十一烷。该化合物可与格氏试剂或锂试剂反应形成相应的5-有机化合物。
- TAA可与氟化1,3,4-恶二唑发生环加成反应，从而生成八氢-2,7-甲呋喃[3,2-c]吡啶。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
E D Thompson et al.
Environmental and molecular mutagenesis, 18(3), 184-199 (1991-01-01)
Three cross-linked polyacrylate polymers containing either methylenebis-acrylamide (MBA), trimethylolpropane triacrylate (TMPTA), or triallylamine (TAA) cross-linkers were tested for genotoxicity with the Salmonella mammalian microsome assay, the L5178Y mouse lymphoma TK +/- assay, the unscheduled DNA synthesis assay in primary cultures
H G Swarts et al.
Biochimica et biophysica acta, 1189(2), 143-151 (1994-01-19)
Tertiary amines like imidazole and triallylamine lower the apparent affinity of K+ in the ATP hydrolysis reaction of pig gastric H,K-ATPase in a pH and amine concentration dependent way. The mechanism and sidedness of this effect was studied by analyzing
Palladium-catalyzed reaction of 1-aza-5-germa-5-organobicyclo [3.3. 3] undecane with aryl bromide.
Kosugi M, et al.
Journal of Organometallic Chemistry, 508(1-2), 255-257 (1996)
Ruthenium-catalyzed synthesis of 2-ethyl-3-methylquinolines from anilines and triallylamine.?
Cho C H, et al.
Tetrahedron Letters, 40(8), 1499-1500 (1999)
Cycloaddition of fluorinated oxadiazoles with triallylamine.
Vasil?ev N V, et al.
Chemistry of Heterocyclic Compounds, 52(9), 750-752 (2016)
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