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蒸汽密度
3.8 (vs air)
质量水平
蒸汽压
1.4 mmHg ( 20 °C)
检测方案
97%
折射率
n20/D 1.588 (lit.)
bp
169 °C (lit.)
mp
−15 °C (lit.)
密度
1.073 g/mL at 25 °C (lit.)
SMILES字符串
Sc1ccccc1
InChI
1S/C6H6S/c7-6-4-2-1-3-5-6/h1-5,7H
InChI key
RMVRSNDYEFQCLF-UHFFFAOYSA-N
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一般描述
苯硫酚是一种有机硫化合物，可用作聚合物生产的中间体。
应用
苯硫酚可以在催化量的辛可宁存在下发生：
- 不对称迈克尔加成到马来酸二异丙酯上形成（s）-（& # 8722；）-苯基硫代琥珀酸二异丙酯，它可进一步转化为（R）-（+）-3，4-环氧-1-丁醇。
- 区域选择性和立体选择性1，4-加成到亚烯基环丙烷上，形成内型-或顺式-乙烯基硫化物加合物，这是合成卡拉哈烯酮的关键步骤。
- 非对映选择性加成到 （S）-N-（& # 945；，& # 946；-不饱和羰基）-& # 947；-[（三苯甲基氧基）甲基]-& # 947；-丁内酯形成相应的& # 946；-（苯硫基）羧酸盐。
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Irrit. 2
WGK
WGK 3
闪点(°F)
122.0 °F
闪点(°C)
50 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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