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一般描述
苯硫酚是一种有机硫化合物,可用作聚合物生产的中间体。
应用
苯硫酚可以在催化量的辛可宁存在下发生:
- 不对称迈克尔加成到马来酸二异丙酯上形成(s)-(& # 8722;)-苯基硫代琥珀酸二异丙酯,它可进一步转化为(R)-(+)-3,4-环氧-1-丁醇。
- 区域选择性和立体选择性1,4-加成到亚烯基环丙烷上,形成内型-或顺式-乙烯基硫化物加合物,这是合成卡拉哈烯酮的关键步骤。
- 非对映选择性加成到 (S)-N-(& # 945;,& # 946;-不饱和羰基)-& # 947;-[(三苯甲基氧基)甲基]-& # 947;-丁内酯形成相应的& # 946;-(苯硫基)羧酸盐。
警示用语:
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
122.0 °F - closed cup
闪点(°C)
50 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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