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Merck
CN

T25003

Sigma-Aldrich

四硝基甲烷

别名:

TNM

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About This Item

线性分子式:
C(NO2)4
CAS号:
分子量:
196.03
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

8.4 mmHg ( 20 °C)

折射率

n20/D 1.438 (lit.)

沸点

126 °C (lit.)

mp

13-14 °C (lit.)

密度

1.637 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

[O-][N+](=O)C([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O

InChI

1S/CN4O8/c6-2(7)1(3(8)9,4(10)11)5(12)13

InChI key

NYTOUQBROMCLBJ-UHFFFAOYSA-N

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应用

烯醇硅醚和芳香族化合物的硝化试剂。用于硫化物到亚砜的光氧化反应。
Reactant involved in:
  • Nitration of electrophilic alkenes
  • Reactions with B-alkylcatecholboranes forming oxime ethers
  • Heterocyclization of electrophilic alkenes
  • Ring opening of aziridines
  • Acts as an electron acceptor in the mechanism of aerobic visible light formic acid oxidation
  • Reactions with vinyl ketones

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Ox. Liq. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis, 1057-1057 (1993)
Tetrahedron Letters, 34, 1859-1859 (1993)
Yuki Takano et al.
Oncotarget, 8(45), 78598-78613 (2017-11-08)
A primary tumor can create a premetastatic niche in distant organs to facilitate the development of metastasis. The mechanism by which tumor cells communicate with host cells to develop premetastatic niches is unclear. We focused on the role of microRNA
J. Chem. Soc. Perkin Trans. II, 1719-1719 (1994)
Nicolas Abello et al.
Journal of proteome research, 8(7), 3222-3238 (2009-05-07)
Protein tyrosine nitration (PTN) is a post-translational modification occurring under the action of a nitrating agent. Tyrosine is modified in the 3-position of the phenolic ring through the addition of a nitro group (NO2). In the present article, we review

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