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Merck
CN

T15601

四氢噻吩

99%

别名:

THT, 噻吩烷, 四氢硫杂茂, 四甲撑硫

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关于此项目

经验公式(希尔记法):
C4H8S
化学文摘社编号:
分子量:
88.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-728-9
Beilstein/REAXYS Number:
102392
MDL number:
Assay:
99%
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InChI key

RAOIDOHSFRTOEL-UHFFFAOYSA-N

InChI

1S/C4H8S/c1-2-4-5-3-1/h1-4H2

SMILES string

C1CCSC1

vapor pressure

18 mmHg ( 25 °C)

assay

99%

refractive index

n20/D 1.504 (lit.)

bp

119 °C (lit.)

mp

−96 °C (lit.)

density

1 g/mL at 25 °C (lit.)

Quality Level

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Application

四氢噻吩可用作合成各种环氧化物及其衍生物的试剂。它可用作合成苯并[n.1.0]双环烷烃的催化剂。

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

55.4 °F - closed cup

flash_point_c

13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A new protocol for the in situ generation of aromatic, heteroaromatic, and unsaturated diazo compounds and its application in catalytic and asymmetric epoxidation of carbonyl compounds. Extensive studies to map out scope and limitations, and rationalization of diastereo-and enantioselectivities.
Aggarwal VK, et al.
Journal of the American Chemical Society, 125(36), 10926-10940 (2003)
Catalytic asymmetric synthesis of epoxides from aldehydes using sulfur ylides with in situ generation of diazocompounds.
Aggarwal VK, et al.
Angewandte Chemie (International Edition in English), 40(8), 1430-1433 (2001)
Tetrahydrothiophene-catalyzed synthesis of benzo [n.1.0] bicycloalkanes.
Ye LW, et al.
The Journal of Organic Chemistry, 72(4), 1335-1340 (2007)
V I Smol'iakova et al.
Eksperimental'naia i klinicheskaia farmakologiia, 73(8), 32-34 (2010-10-06)
Carbon tetrachloride-induced hepatitis in rats is accompanied by blood hyperviscosity syndrome development. A course intragastric administration of thiophane under these conditions prevents the increase in whole blood viscosity by normalizing the microrheological indices (deformability and aggregation of erythrocytes), which is
James C Ritchie et al.
Neuropsychopharmacology : official publication of the American College of Neuropsychopharmacology, 28(1), 22-33 (2002-12-24)
Using purified enzyme preparations, we investigated the actions of angiotensin-converting enzyme, aminopeptidase N, and endopeptidase 24.11 on corticotropin-releasing factor (CRF). The effects of inhibition of these enzymes on CRF action in rat anterior pituitary cultures were also determined. Finally, specific

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