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Merck
CN

RNI00145

Sigma-Aldrich

(2S)-2-Phenyl-2,3-dihydroimidazo[2,1-b][1,3]benzothiazole

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别名:
(S)-BTM
经验公式(希尔记法):
C15H12N2S
分子量:
252.33
MDL编号:
UNSPSC代码:
12352200
PubChem化学物质编号:

形式

solid

SMILES字符串

C12=CC=CC=C1SC3=N[C@@H](C4=CC=CC=C4)CN23

InChI

1S/C15H12N2S/c1-2-6-11(7-3-1)12-10-17-13-8-4-5-9-14(13)18-15(17)16-12/h1-9,12H,10H2/t12-/m1/s1

InChI key

YGCWPCVAVSIFLO-GFCCVEGCSA-N

应用

Organocatalyst for the kinetic resolution of secondary alcohols by acylation with anhydrides.

Kinetic Resolution of Secondary Alcohols Using Amidine-Based Catalysts

其他说明

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

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象形图

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警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Diastereoselective and Enantioselective Silylation of 2-Arylcyclohexanols
Wang L, et al.
Organic Letters, 17 (10), 2408?2411-2408?2411 (2015)

商品

We are proud to offer the isothiourea organocatalyst homobenzotetramisole (HBTM) as part of our asymmetric catalysis portfolio in both (R) and (S) enantiomeric forms.

作为我们不对称催化产品组合的一部分,我们很自豪地以(R)和(S)对映体形式提供异硫脲有机催化剂均苯并四咪唑(HBTM)。

相关内容

The main focus of research in the Birman group is on the de novo design of asymmetric catalysts and reagents. As part of this effort, they have developed Amidine-Based Catalysts, or ABCs, and demonstrated their high enantioselectivity in many asymmetric acyl transfer reactions. The versatility, accessibility, and ease of structural modification of ABCs have attracted the interest of a number of other research groups worldwide, which has led to further expansion of their synthetic utility.

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

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