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Merck
CN

R2252

氯化铷

ReagentPlus®, ≥99.0% (metals basis)

别名:

一氯化铷

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线性分子式:
RbCl
化学文摘社编号:
分子量:
120.92
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-240-9
MDL number:
Assay:
≥99.0% (metals basis)
Form:
powder
Solubility:
H2O: soluble, clear to slightly hazy
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产品名称

氯化铷, ReagentPlus®, ≥99.0% (metals basis)

InChI key

FGDZQCVHDSGLHJ-UHFFFAOYSA-M

InChI

1S/ClH.Rb/h1H;/q;+1/p-1

SMILES string

[Cl-].[Rb+]

product line

ReagentPlus®

assay

≥99.0% (metals basis)

form

powder

impurities

≤10000 ppm Metal Trace Analysis (ICP)

mp

715 °C (lit.)

solubility

H2O: soluble, clear to slightly hazy

density

2.8 g/mL at 25 °C (lit.)

absorption

≤0.4 at 280 in H2O at 50%

Quality Level

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Application

氯化铷可用作掺杂剂合成氧化镁纳米颗粒。

可用于增强有机发光二极管(OLED)性能。比如,在多层OLED(ITO/NPB/Alq3/Al)中插入一薄层RbCl可大幅提高其电致发光效率,因RbCl层提供的陷阱位点(trap sites)可降低电子注入势垒并增强复合速率。

氯化铷(RbCl)也可用作非侵入性生物标志物。

还用于研究仓鼠中Rb的睡眠时型影响。

General description

氯化铷是一种碱金属卤化盐,是水溶性铷晶体的优异来源。广泛用于生物医学研究、电化学、纳米材料合成和汽油行业。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. What is Rubidium Chloride, Product R2252, soluble in?

    This product is soluble in water (100 mg/ml), yielding a clear to slightly hazy, colorless to very faint yellow solution.  Also, per the chemicals encyclopedia published by the Royal Society of Chemistry, 13th Edition, 1 gram will dissolve in 90ml of Methanol or 1650ml of Ethanol.

  4. How is Rubidium Chloride, Product R2252, used in the area of Material Science?

    Rubidium Chloride has been used to prepare molecular nanowires as potential precursors of nanoscale devices.  (Akutagawa, T., et al., Formation of oriented molecular nanowires on mica surface. Proc. Natl. Acad. Sci. USA, 99(8), 5028-5033 (2002).)

  5. Do I need to be aware of anything when handling Rubidium Chloride, Product R2252?

    Yes, Rubidium Chloride is hygroscopic and will absorb water.  This should be taken into account when handling and storing this compounds.  Flushing the head space of the bottle with Nitrogen and storing it in a dessicator will help to keep the material from absorbing moisture.

  6. How is Product R2252, Rubidium Chloride made?

    There are many techniques and methods for Rubidium Chloride - here a few: One way to make rubidium chloride is to react the hydroxide with hydrochloric acid. The resulting salt can then be purified by recrystallization.RbOH(aq) + HCl(aq) -> RbCl(aq) + H2O(l)Rubidium(I) bromide can also be made by the neutralization of rubidium(I) carbonate with hydrobromic acid. The resulting salt can then be purified by recrystallization.Rb2(CO3)(aq) + 2HBr(aq) -> 2RbBr(aq) + H2O(l) + CO2(g)While not a normal route of preparation because of the expense, rubidium metal reacts vigorously with all the halogens to form rubidium halides. So, it burns with chlorine, Cl2, to form rubidium(I) chloride, RbCl.2Rb(s) + Cl2(g) -> 2RbCl(s)

  7. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  8. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  9. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Rubidium chloride fuses split circadian activity rhythms in hamsters housed in bright constant light
Hallonquist J, et al.
Chronobiology International, 11(2), 65-71 null
Marking bark beetle parasitoids within the host plant with rubidium for dispersal studies
Hougardy E, et al.
Entomologia Experimentalis et Applicata, 108(2), 107-114 (2003)
The effect of rubidium chloride on properties of organic light-emitting diodes
Lu Z, et al.
Solid-State Electron, 53(11), 1154-1158 (2009)
Grazyna Bystrzejewska-Piotrowska et al.
Journal of environmental radioactivity, 99(7), 1185-1191 (2008-03-18)
Ex vitro cultures of Pleurotus eryngii were carried out under controlled conditions using sterile medium composed of barley seeds. The influence of alkali and alkaline earth element salts (CsCl, KCl, NaCl, RbCl, and CaCl(2)) and tetraethylammonium chloride on incorporation of
M L Główka et al.
Acta crystallographica. Section D, Biological crystallography, 61(Pt 4), 433-441 (2005-04-05)
Gramicidin D (gD) is a naturally occurring ionophoric antibiotic that forms membrane channels specific for monovalent cations. The crystal structure of the RbCl complex of gD has been determined at 1.14 A resolution from low-temperature (100 K) synchrotron-radiation data with

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