蒸汽密度
3 (vs air)
质量水平
检测方案
98%
自燃温度
649 °F
expl. lim.
9 %
折射率
n20/D 1.406 (lit.)
bp
118-119 °C (lit.)
密度
0.812 g/mL at 25 °C (lit.)
SMILES字符串
CCCC(C)O
InChI
1S/C5H12O/c1-3-4-5(2)6/h5-6H,3-4H2,1-2H3
InChI key
JYVLIDXNZAXMDK-UHFFFAOYSA-N
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应用
2-戊醇是一种仲醇，可用作：
- 一种氢供体，通过钌/氧化钌/碳催化剂上的糠醛催化转移氢，合成甲基呋喃
- 一种用于一锅法合成溴化衍生物 3-二氧戊环的试剂。
- 一种用于合成有机分子的有机溶剂，如 2，4-二氨基嘧啶和4-氮杂-鬼臼毒素。
警示用语：
Warning
危险分类
Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 2
闪点(°F)
93.2 °F
闪点(°C)
34 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
One-pot synthesis of ?-bromoacetals of ketones from secondary alcohols and 1, 3-dibromo-5, 5-dimethylhydantoin (DBDMH) in ethylene glycol.
Han B, et al.
Synthetic Communications, 47(24), 2387-2394 (2017)
Multicomponent assembly of 4-aza-podophyllotoxins: a fast entry to highly selective and potent anti-leukemic agents.
Jeedimalla N, et al.
European Journal of Medicinal Chemistry, 106, 167-179 (2015)
Structure-based design and synthesis of 2, 4-diaminopyrimidines as EGFR L858R/T790M selective inhibitors for NSCLC.
Chen L, et al.
European Journal of Medicinal Chemistry, 140, 510-527 (2017)
Effect of hydrogen donor on liquid phase catalytic transfer hydrogenation of furfural over a Ru/RuO2/C catalyst.
Panagiotopoulou P, et al.
J. Mol. Catal. A: Chem., 392, 223-228 (2014)
Xiao-Hong Chen et al.
PloS one, 9(4), e94543-e94543 (2014-04-18)
A novel carbonyl reductase (AcCR) catalyzing the asymmetric reduction of ketones to enantiopure alcohols with anti-Prelog stereoselectivity was found in Acetobacter sp. CCTCC M209061 and enriched 27.5-fold with an overall yield of 0.4% by purification. The enzyme showed a homotetrameric
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