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Merck
CN

P78

Sigma-Aldrich

棕榈酰氯

98%

别名:

十六酰氯

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About This Item

线性分子式:
CH3(CH2)14COCl
CAS号:
分子量:
274.87
Beilstein:
972409
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

折射率

n20/D 1.452 (lit.)

沸点

88-90 °C/0.2 mmHg (lit.)

mp

11-13 °C (lit.)

密度

0.906 g/mL at 25 °C (lit.)

SMILES字符串

CCCCCCCCCCCCCCCC(Cl)=O

InChI

1S/C16H31ClO/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16(17)18/h2-15H2,1H3

InChI key

ARBOVOVUTSQWSS-UHFFFAOYSA-N

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应用

棕榈酰氯可用于:
  • 通过立体选择性烯烃交叉复分解,将碳链引入糖鞘脂半乳糖神经酰胺。
  • 通过环氧乙烷的区域选择性开环,制备单酰基和1,3-对称的三酰基甘油。

也可用于全合成以下物质:
  • 猴头菌酮J(Hericenone J)和5′ -脱氧代猴头菌酮 C(hericene A)。
  • 甘露糖脂。
  • 分枝杆菌素S和分枝杆菌素T等同物,其具有儿茶酚-甘氨酸基团而非天然存在分枝杆菌素所含的酚-恶唑啉基团。

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

补充剂危害

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

320.0 °F - closed cup

闪点(°C)

160 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Kyoung-Hwa Choi et al.
Carbohydrate polymers, 246, 116487-116487 (2020-08-05)
The purpose of this study was to investigate the improvement in the hydrophobicity of cellulose through gas grafting treatment with long chain fatty acid chloride using high pressure during pressing at high temperature. To do this, the gas grafting treatment
Regioselective opening of an oxirane system with trifluoroacetic anhydride. A general method for the synthesis of 2-monoacyl-and 1, 3-symmetrical triacylglycerols
Stamatov SD and Stawinski J
Tetrahedron, 61(15), 3659-3669 (2005)
Rapid access to 6-bromo-5, 7-dihydroxyphthalide 5-methyl ether by a CuBr2-mediated multi-step reaction: concise total syntheses of hericenone J and 5′ -deoxohericenone C (hericene A)
Kobayashi S, et al.
Tetrahedron, 67(47), 9087-9092 (2011)
Takeshi Harayama et al.
Journal of lipid research, 56(7), 1370-1379 (2015-05-30)
The surfactant proteins (SPs), SP-B and SP-C, are important components of pulmonary surfactant involved in the reduction of alveolar surface tension. Quantification of SP-B and SP-C in surfactant drugs is informative for their quality control and the evaluation of their
Total syntheses of seminolipid and its analogues by using 2, 6-bis (trifluoromethyl) phenylboronic acid as protective reagent
Shimada N, et al.
Organic & Biomolecular Chemistry, 17(31), 7325-7329 (2019)

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