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质量水平
检测方案
98%
旋光性
[α]/D 35 to 54, neat
光学纯度
ee: ≥85% (GLC)
自燃温度
491 °F
折射率
n20/D 1.465 (lit.)
bp
155-156 °C (lit.)
mp
−62 °C (lit.)
密度
0.858 g/mL at 20 °C (lit.)
SMILES字符串
CC1=CC[C@@H]2C[C@H]1C2(C)C
InChI
1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9-/m1/s1
InChI key
GRWFGVWFFZKLTI-RKDXNWHRSA-N
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一般描述
(+)-α-蒎烯是一种单萜，是生物动力燃料的前体。 它会发生臭氧分解，产生二次有机气溶胶（SOA）物质。
应用
(+)-α-蒎烯可用于：
- 制备手性有机硼烷，用于合成光学活性化合物和Suzuki偶联。
- 作为芳醛的烯丙基化反应的催化剂，用于合成手性吡啶型N-氧化物。
- 合成2,3-蒎烷二胺，是多种催化剂和试剂的手性助剂。
(+)-α-蒎烯已被用于耐性试验中，以检测Marinobacter aquaeolei的基因，用于一种耐受蒎烯的大肠杆菌的工程化。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis and characterization of novel chiral 1, 2-diamines derived from α-pinene.
Suzuki T, et al.
Chemistry Letters (Jpn), 34(11), 1476-1477 (2005)
Coating of soot and (NH4)2SO4 particles by ozonolysis products of a-pinene.
Saathoff, H., et al.
Journal of Aerosol Science, 34(10), 1297-1321 (2003)
Chiral synthesis via organoboranes. 18. Selective reductions. 43. Diisopinocampheylchloroborane as an excellent chiral reducing reagent for the synthesis of halo alcohols of high enantiomeric purity. A highly enantioselective synthesis of both optical isomers of Tomoxetine, Fluoxetine, and Nisoxetine.
Srebnik M, et al.
The Journal of Organic Chemistry, 53(13), 2916-2920 (1988)
New pyridine-derived N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes.
Malkov A V, et al.
J. Mol. Catal. A: Chem., 196(1-2), 179-186 (2003)
Ariel M Langevin et al.
Journal of bacteriology, 200(1) (2017-10-19)
Stress tolerance studies are typically conducted in an all-or-none fashion. However, in realistic settings-such as in clinical or metabolic engineering applications-cells may encounter stresses at different rates. Therefore, how cells tolerate stress may depend on its rate of appearance. To
Chromatograms
suitable for GCsuitable for GCsuitable for GC我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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