P35405
二苯基亚砜
96%
别名:
苯基亚砜
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线性分子式:
(C6H5)2SO
化学文摘社编号:
分子量:
202.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-415-9
Beilstein/REAXYS Number:
1908444
MDL number:
产品名称
二苯基亚砜, 96%
InChI key
JJHHIJFTHRNPIK-UHFFFAOYSA-N
InChI
1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
SMILES string
O=S(c1ccccc1)c2ccccc2
assay
96%
form
crystals
bp
206-208 °C/13 mmHg (lit.)
mp
69-71 °C (lit.)
Quality Level
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Application
- 制备放射性化合物：在由 [（11）C]碘甲烷合成[（11）C]氰化物的过程中二苯亚砜起一定作用Kikuchi et al., 2022）。
- 催化氧化过程：考察了二苯基硫的光催化和催化氧化形成亚砜的过程，重点介绍了过氧化氢和TiO2 多形体（polymorph）在优化化学过程中的有效性（Mikrut et al., 2022）。
- 电介质性质研究：有关高有机硫煤的电介质性质研究重点关注了硫化合物（包括二苯亚砜）的改造，增进了我们对材料科学能量领域的理解（Cai et al., 2019）。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
S Yoshihara et al.
Archives of biochemistry and biophysics, 249(1), 8-14 (1986-08-15)
To characterize the properties of diphenyl sulfoxide (DPSO) as a new type of electron acceptor for guinea pig liver aldehyde oxidase (AO), we compared the kinetics of the reductions of DPSO and other classical electron acceptors such as O2 and
J A Kozlowski et al.
Bioorganic & medicinal chemistry letters, 10(20), 2255-2257 (2000-10-31)
Structure activity studies on [4-(phenylsulfonyl)phenyl]methylpiperazine led to the discovery of 4-cyclohexyl-alpha-[4-[[4-methoxyphenyl(S)-sufinyl]phenyl]-1-pi perazineacetonitrile, 1, an M2 selective muscarinic antagonist. Affinity at the cloned human M2 receptor was 2.7 nM; the M1/M2 selectivity is 40-fold.
S Yoshihara et al.
Drug metabolism and disposition: the biological fate of chemicals, 18(6), 876-881 (1990-11-01)
To evaluate the metabolic capacity of intact guinea pig liver under normoxic and hypoxic conditions, oxidative and reductive metabolism of diphenyl sulfoxide (DPSO) was studied by the nonrecirculating perfusion method in situ. DPSO was exclusively converted into diphenyl sulfone (DPSO2)
Martin A Fascione et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(10), 2987-2997 (2012-02-02)
Sulfoxides are frequently used in organic synthesis as chiral auxiliaries and reagents to mediate a wide variety of chemical transformations. For example, diphenyl sulfoxide and triflic anhydride can be used to activate a wide range of glycosyl donors including hemiacetals
Wen-Xian Li et al.
Luminescence : the journal of biological and chemical luminescence, 26(6), 754-761 (2011-05-14)
A novel ternary complex, TbL(5) L'(ClO(4))(3) · 3H(2)O, two binary complexes, TbL(7) (ClO(4))(3) · 3H(2)O and TbL'(3.5) (ClO(4))(3) · 4H(2)O has been synthesized (using diphenyl sulphoxide as the first ligand L, bipyridine as the second ligand L'). Their composition was
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