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质量水平
检测方案
≥98%
bp
371 °C (lit.)
mp
182-187 °C (lit.)
SMILES字符串
N1c2ccccc2Sc3ccccc13
InChI
1S/C12H9NS/c1-3-7-11-9(5-1)13-10-6-2-4-8-12(10)14-11/h1-8,13H
InChI key
WJFKNYWRSNBZNX-UHFFFAOYSA-N
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一般描述
吩噻嗪是多功能的合成砌块，含多个修饰位点方便官能化。独特的蝴蝶状构型和富电子性质适合光电领域。因其可进行快速、可逆的电子转移反应，广泛用作有机发光装置和太阳能电池的光敏材料。
应用
吩噻嗪可用于：
- 通过C-N键与咔唑连接，提高有机发光装置的空穴迁移率和热稳定性。
- 制备基于CMA（卡宾-金属-酰胺）的白光OLED。
- 作为起始材料合成二醛单体。单体用于制备共轭聚合物，用作PLED的发光层。
- 用作共轭树枝状聚合物的合成砌块，用于发光装置的研发。
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT RE 2 Oral
靶器官
Blood
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Alexander S Romanov et al.
Chemical science, 11(2), 435-446 (2020-03-20)
Conformationally flexible "Carbene-Metal-Amide" (CMA) complexes of copper and gold have been developed based on a combination of sterically hindered cyclic (alkyl)(amino)carbene (CAAC) and 6- and 7-ring heterocyclic amide ligands. These complexes show photoemissions across the visible spectrum with PL quantum
Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A, 237, 419-419 (1993)
Rajendra Kumar Konidena et al.
The Journal of organic chemistry, 80(11), 5812-5823 (2015-05-08)
A series of thienylphenothiazine decorated carbazoles were synthesized and characterized by optical, electrochemical, thermal, and theoretical investigations. Absorption spectra of the compounds are influenced by the substitution pattern and chromophore number density. Compounds containing 2,7-substitution exhibited red-shifted absorption, while the
Structure-induced optoelectronic properties of phenothiazine-based materials
Revoju, et al.
Journal of Material Chemistry C, 8(44), 15486-15506 (2020)
Synthesis of p-type conjugated dendrimers bearing phenothiazine moiety at the periphery and their light-emitting device characterization
Dong Hoon Choi, et al.
Synthetic Metals, 157(8), 332-335 (2007)
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