一般描述
1,7-辛二烯可作为乙烯的交联剂和来源,用于不同的Mori条件下的CEYM相关反应。
应用
用1,7-辛二烯研究了一系列简单的二前缀开环复分解的结构和反应速率。它也被用作研究等离子体聚合制备的微图案化表面。
警示用语:
Danger
危险声明
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2
WGK
WGK 3
闪点(°F)
50.0 °F
闪点(°C)
10 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chemistry (Weinheim an der Bergstrasse, Germany), 18(35), 10991-10997 (2012-08-02)
The use of 1,7-octadiene as an in situ source of ethylene led us to develop a novel multicomponent tandem cross-enyne metathesis (CEYM)-Diels-Alder reaction. The process can be considered a relay metathesis, in which the ethylene liberated in the ring-closing metathesis
Physiological research, 58(5), 669-684 (2008-12-20)
Micropatterned surfaces have been used as a tool for controlling the extent and strength of cell adhesion, the direction of cell growth and the spatial distribution of cells. In this study, chemically micropatterned surfaces were prepared by successive plasma polymerization
Nanoscale, 8(8), 4635-4642 (2016-02-09)
The wetting of a material can be tuned by changing the roughness on its surface. Recent advances in the field of nanotechnology open exciting opportunities to control macroscopic wetting behaviour. Yet, the benchmark theories used to describe the wettability of
Langmuir : the ACS journal of surfaces and colloids, 33(35), 8790-8798 (2017-05-30)
The role surface capping molecules play in dictating the optical properties of semiconductor nanocrystals (NCs) is becoming increasingly evident. In this paper the role of surface capping molecule polarity on the optical properties of germanium NCs (Ge NCs) is explored.
Chemical communications (Cambridge, England), 46(38), 7145-7147 (2010-09-08)
In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM
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