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质量水平
检测方案
99%
形式
solid
bp
96 °C (lit.)
mp
44-46 °C (lit.)
SMILES字符串
C1C[C@H]2C[C@@H]1C=C2
InChI
1S/C7H10/c1-2-7-4-3-6(1)5-7/h1-2,6-7H,3-5H2/t6-,7+
InChI key
JFNLZVQOOSMTJK-KNVOCYPGSA-N
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一般描述
双环[2.2.1]庚-2-烯是一种环状烯烃，用于过渡金属催化的烯烃二聚反应中。
双环[2.2.1]庚-2-烯 (降冰片烯)在甲基铝氧烷（MAO）活化的氯苯中 与 Co(II) 化合物和 金属茂 [η5-(C5Me5)Co-η2-Cl]2的烯基聚合反应已有报道。已有报道称在乙烯参与下，Co（II）可催化双环[2.2.1]庚-2-烯的聚合。
双环[2.2.1]庚-2-烯 (降冰片烯)在甲基铝氧烷（MAO）活化的氯苯中 与 Co(II) 化合物和 金属茂 [η5-(C5Me5)Co-η2-Cl]2的烯基聚合反应已有报道。已有报道称在乙烯参与下，Co（II）可催化双环[2.2.1]庚-2-烯的聚合。
应用
双环[2.2.1]庚-2-烯可用于制备顺式,外-2,3-二芳基取代的双环[2.2.1]庚烷或双环[2.2.1]庚-2-烯。
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Repr. 2
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
A new palladium catalyzed synthesis of cis, exo-2, 3-diarylsubstituted bicyclo [2.2. 1] heptanes or bicyclo [2.2. 1] hept-2-enes.
Catellani M, et al.
Tetrahedron, 45(16), 5263-5268 (1989)
Co (II)-catalyzed polymerization of bicyclo [2.2. 1] hept-2-ene in the presence of ethene.
Alt FP and Heitz W.
Acta Polym., 49(9), 477-481 (1998)
The Non-planarity of the Bicyclo [2.2. 1] hept-2-ene Double bond. Crystal Structures of Bicyclo [2.2. 2] oct-2-ene, Bicyclo [2.2. 1] hept-2-ene, and Bicyclo [2.1. 1] hex-2-ene Systems
Pinkerton, et al.
Helvetica Chimica Acta, 67, 1136-1153 (1984)
A novel catalytic route to 2-bicyclo [2.2. 1] hept-2-ylidenebicyclo [2.2. 1]-heptane involving CH bond activation of bicyclo [2.2. 1] hept-2-ene
Malinowska, et al.
Journal of Molecular Catalysis. B, Enzymatic, 226, 259-262 (2005)
P Veeraraghavan Ramachandran et al.
Organic letters, 12(20), 4474-4477 (2010-09-21)
The first boron-mediated enolization-aldolization of 3,3,3-trifluoropropionates has been reported. The preparation and application of bis-exo-bicyclo[2.2.1]heptan-2-ylboron triflate as a superior reagent for diastereospecific enolization has also been described.
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