N1909
1-萘甲酸
96%
别名:
1-萘酸
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关于此项目
线性分子式:
C10H7CO2H
化学文摘社编号:
分子量:
172.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-681-9
Beilstein/REAXYS Number:
1908896
MDL number:
Assay:
96%
Form:
powder
产品名称
1-萘甲酸, 96%
InChI
1S/C11H8O2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H,(H,12,13)
InChI key
LNETULKMXZVUST-UHFFFAOYSA-N
SMILES string
OC(=O)c1cccc2ccccc12
assay
96%
form
powder
bp
300 °C (lit.)
mp
157-160 °C (lit.)
Quality Level
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Application
1-萘甲酸可作为以下应用的反应剂：
- 在铑催化剂存在下，与炔烃通过脱水环化反应制备萘嵌苯酮。
- 使用Rh催化剂，与2-丁炔通过有氧的氧化环化反应制备异香豆素衍生物。
- 与N,O-二甲基羟胺和三氯化磷反应制备N-甲氧基-N-甲基-1-萘甲酰胺（Weinreb酰胺）。
- 通过Birch还原反应制备1,4-二氢-1-萘羧酸。
Other Notes
残留物为 2-萘甲酸
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Niu T, et al.
Synthesis, 46, 320-330 (2014)
The Metal-Ammonia Reduction of 1-Naphthoic Acid
Rabideau PW, et al.
Synthetic Communications, 10, 627-632 (1980)
Regioselective synthesis of isocoumarins by ruthenium-catalyzed aerobic oxidative cyclization of aromatic acids with alkynes
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Chemical Communications (Cambridge, England), 48, 2030-2032 (2012)
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Nature communications, 11(1), 28-28 (2020-01-09)
The mechanisms of triplet energy transfer across the inorganic nanocrystal/organic molecule interface remain poorly understood. Many seemingly contradictory results have been reported, mainly because of the complicated trap states characteristic of inorganic semiconductors and the ill-defined relative energetics between semiconductors
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