M87509
3-丁烯-2-酮
contains 0.3-1.0% hydroquinone as stabilizer, technical grade, 90%
别名:
丁烯酮, 甲基乙烯基酮
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线性分子式:
CH2=CHCOCH3
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506021
Assay:
90%
Form:
liquid
InChI
1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3
SMILES string
CC(=O)C=C
InChI key
FUSUHKVFWTUUBE-UHFFFAOYSA-N
grade
technical grade
vapor density
1.3 (vs air)
vapor pressure
310 mmHg ( 55 °C), 71 mmHg ( 20 °C)
assay
90%
form
liquid
contains
0.3-1.0% hydroquinone as stabilizer
expl. lim.
15.64 %
impurities
<7% water
Quality Level
refractive index
n20/D 1.411 (lit.)
bp
81 °C (lit.)
solubility
H2O: soluble
density
0.864 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
3-Buten-2-one can undergo conjugate addition with methanol over the solid base catalysts to afford 4-methoxy-butan-2-one. It can also undergo coupling reaction with alkyltins and alkynes in the presence of a nickel complex to form stereo-defined conjugated enynes.
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
19.4 °F - closed cup
flash_point_c
-7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
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此项目有
Synthesis of stereodefined enynes by the nickel-catalyzed coupling reaction of alkynyltins, alkynes, and enones.
Ikeda SI
Journal of the American Chemical Society, 116(13), 5975-5976 (1994)
Conjugate addition of methanol to 3-buten-2-one over solid base catalysts.
Kabashima H, et al.
Applied Catalysis A: General, 214(1), 121-124 (2001)
David Rabuka et al.
Journal of the American Chemical Society, 130(18), 5947-5953 (2008-04-12)
The controlled addition of structurally defined components to live cell membranes can facilitate the molecular level analysis of cell surface phenomena. Here we demonstrate that cell surfaces can be engineered to display synthetic bioactive polymers at defined densities by exogenous
Ying Liu et al.
Environmental science & technology, 43(1), 75-81 (2009-02-13)
It is important to identify the sources of reactive volatile organic compounds (VOCs) in Beijing for effective ground-level ozone abatement. In this paper, semihourly measurements of hydrocarbons and oxygenated VOCs (OVOCs) were taken at an urban site in Beijing in
Richard M LoPachin et al.
Toxicological sciences : an official journal of the Society of Toxicology, 98(2), 561-570 (2007-05-24)
Conjugated Type-2 alkenes, such as acrylamide (ACR), are soft electrophiles that produce neurotoxicity by forming adducts with soft nucleophilic sulfhydryl groups on proteins. Soft-soft interactions are governed by frontier molecular orbital characteristics and can be defined by quantum mechanical parameters
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