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线性分子式:
CH2=CHCOCH3
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506021
Assay:
90%
Form:
liquid
InChI
1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3
SMILES string
CC(=O)C=C
InChI key
FUSUHKVFWTUUBE-UHFFFAOYSA-N
grade
technical grade
vapor density
1.3 (vs air)
vapor pressure
310 mmHg ( 55 °C), 71 mmHg ( 20 °C)
assay
90%
form
liquid
contains
0.3-1.0% hydroquinone as stabilizer
expl. lim.
15.64 %
impurities
<7% water
Quality Level
refractive index
n20/D 1.411 (lit.)
bp
81 °C (lit.)
solubility
H2O: soluble
density
0.864 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
3-Buten-2-one can undergo conjugate addition with methanol over the solid base catalysts to afford 4-methoxy-butan-2-one. It can also undergo coupling reaction with alkyltins and alkynes in the presence of a nickel complex to form stereo-defined conjugated enynes.
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
19.4 °F - closed cup
flash_point_c
-7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Synthesis of stereodefined enynes by the nickel-catalyzed coupling reaction of alkynyltins, alkynes, and enones.
Ikeda SI
Journal of the American Chemical Society, 116(13), 5975-5976 (1994)
Conjugate addition of methanol to 3-buten-2-one over solid base catalysts.
Kabashima H, et al.
Applied Catalysis A: General, 214(1), 121-124 (2001)
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