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Merck
CN

M50850

Sigma-Aldrich

2-甲基咪唑

99%

别名:

2-甲基-1,3-氮杂茂

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About This Item

经验公式(希尔记法):
C4H6N2
CAS号:
分子量:
82.10
Beilstein:
1368
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

<1 mmHg ( 0 °C)

质量水平

检测方案

99%

bp

267-268 °C (lit.)

mp

142-143 °C (lit.)

SMILES字符串

Cc1ncc[nH]1

InChI

1S/C4H6N2/c1-4-5-2-3-6-4/h2-3H,1H3,(H,5,6)

InChI key

LXBGSDVWAMZHDD-UHFFFAOYSA-N

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应用

2-甲基咪唑可用作:      
  • 一种配位调节剂,用于制备2D金属有机框架材料-5 (MOF-5)纳米片,该纳米片是Knoevenagel缩合反应的高效催化剂。      
  • 碱性诱导剂,用于合成可作为析氧反应活性电催化剂的无定形的FeCoNi三元氢氧化物纳米片。      
  • 与水结合的一种溶剂体系,用于合成可潜在应用于气体分离的沸石咪唑酯骨架结构-8(ZIF-8)膜材料。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1C

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Reda M Abdelhameed et al.
Journal of colloid and interface science, 552, 494-505 (2019-06-04)
Removal of naphthols, as one of the most common pharmaceutical intermediates which released in the wastewater, is in the top priority for the time being. In the current study, zeolitic imidazole frameworks (ZIF-8, Zn & ZIF-67, Co) were directly prepared
Kyo Sung Park et al.
Proceedings of the National Academy of Sciences of the United States of America, 103(27), 10186-10191 (2006-06-27)
Twelve zeolitic imidazolate frameworks (ZIFs; termed ZIF-1 to -12) have been synthesized as crystals by copolymerization of either Zn(II) (ZIF-1 to -4, -6 to -8, and -10 to -11) or Co(II) (ZIF-9 and -12) with imidazolate-type links. The ZIF crystal
Saleh A Ahmed et al.
Scientific reports, 9(1), 19372-19372 (2019-12-20)
In this work, we have successfully synthesized a bimetallic (Zinc and Cobalt) Zeolitic Imidazolate Framework (Zn50Co50-ZIF), a class in a wider microporous Metal-Organic Framework (MOF) family. The synthesized nanostructures maintain both water stability like ZIF-8 (solely Zn containing) and charge
Janosch Cravillon et al.
Angewandte Chemie (International ed. in English), 50(35), 8067-8071 (2011-07-13)
Prenucleation clusters: in situ synchrotron X-ray scattering with a one-second time resolution revealed the occurrence of nano-sized clusters during the nucleation and early growth of nanocrystals of a zeolitic imidazolate framework (ZIF). The complex crystallization process exhibits similarities with crystallization processes
M van Gastel et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 4(3), 257-265 (1999-08-10)
Frozen solutions of the azurin mutant His117Gly in the presence of excess of methyl-substituted imidazoles have been investigated by electron spin-echo envelope modulation (ESEEM) spectroscopy at 9 GHz. The addition of imidazole is known to reconstitute a blue-copper site and

商品

金属有机骨架是配位聚合物的一部分,代表了大量替代能源应用的一个强大的新工具。通过提供定制的高表面积材料的简单的合成策略可以很容易获得MOF。

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

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