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Merck
CN

M50834

Sigma-Aldrich

1-甲基咪唑

greener alternative

ReagentPlus®, 99%

别名:

N-Methylimidazole

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About This Item

经验公式(希尔记法):
C4H6N2
CAS号:
分子量:
82.10
Beilstein:
105197
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

生物来源

synthetic

质量水平

蒸汽压

0.4 mmHg ( 20 °C)

产品线

ReagentPlus®

检测方案

99%

形式

liquid

自燃温度

977 °F

expl. lim.

15.7 %

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

折射率

n20/D 1.495 (lit.)

bp

198 °C (lit.)

mp

−6 °C (lit.)

溶解性

water: soluble

密度

1.03 g/mL at 25 °C (lit.)

环保替代产品分类

SMILES字符串

Cn1ccnc1

InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

InChI key

MCTWTZJPVLRJOU-UHFFFAOYSA-N

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一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品具有增强催化作用。点击此处,查看更多详情。

应用

用作在有氧条件下铜催化的、更环保的醇氧化过程中的助催化剂。

铜(I)/ABNO催化的有氧醇氧化:减轻Cu/TEMPO催化剂系统的空间和电子约束

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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说明
价格

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


分析证书(COA)

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Daniele Hasler et al.
Molecular cell, 77(5), 1014-1031 (2020-02-06)
The La-related protein 7 (LARP7) forms a complex with the nuclear 7SK RNA to regulate RNA polymerase II transcription. It has been implicated in cancer and the Alazami syndrome, a severe developmental disorder. Here, we report a so far unknown
Yan Liu et al.
Plants (Basel, Switzerland), 9(3) (2020-03-19)
Small RNA (sRNA) turnover is a key but poorly understood mechanism that determines the homeostasis of sRNAs. Animal XRN genes contribute the degradation of sRNAs, AtXRN2 and AtXRN3 also contribute the pri-miRNA processing and miRNA loop degradation in plants. However
Fumitoshi Shibahara et al.
The Journal of organic chemistry, 77(19), 8815-8820 (2012-09-15)
Synthetic methods for triarylated azoles containing three different aryl groups via one-pot sequential multiple C-H bond arylations are described. The one-pot sequential diarylation of C5-monoarylated azoles was achieved by the simple sequential addition of two different aryl iodides with a
Chih-Chin Tsou et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(47), 13358-13366 (2011-10-19)
S-nitrosation of the coordinated thiolate of dinitrosyl iron complexes (DNICs) to generate S-nitrosothiols (RSNOs) was demonstrated. Transformation of [{(NO)(2)Fe(μ-StBu)}(2)] (1-tBuS) into the {Fe(NO)(2)}(9) DNIC [(NO)(2)Fe(StBu)(MeIm)] (2-MeIm) occurs under addition of 20 equiv of 1-methylimidazole (MeIm) into a solution of 1-tBuS in
Bhaskar Sharma et al.
The journal of physical chemistry. A, 115(10), 1971-1984 (2011-02-22)
Quantum chemical [MP2(FULL)/6-311++G-(d,p)] calculations are done on the binding of hydrated Li(+), Na(+), K(+), Mg(2+), Cu(+), and Zn(2+) metal ions with biologically relevant heteroaromatics such as imidazole and methylimidazole. The computed interaction energies are found to be in good agreement

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