M50001
甲基肼
98%
别名:
MMH
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关于此项目
线性分子式:
CH3NHNH2
化学文摘社编号:
分子量:
46.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-471-4
Beilstein/REAXYS Number:
635645
MDL number:
Assay:
98%
InChI key
HDZGCSFEDULWCS-UHFFFAOYSA-N
InChI
1S/CH6N2/c1-3-2/h3H,2H2,1H3
SMILES string
CNN
vapor density
1.6 (vs air)
vapor pressure
37.5 mmHg ( 20 °C)
assay
98%
autoignition temp.
385 °F
expl. lim.
97 %
refractive index
n20/D 1.4325 (lit.)
bp
88-90 °C (lit.)
density
0.875 g/mL at 20 °C (lit.)
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Application
甲基肼可用于诱导 β-三氟甲基-β,β-二取代烯酮的不对称需氧环氧化，合成对映选择性三氟甲基-取代的环氧化物。 也可用于合成1-甲基-3,5-二硝基-1H-1,2,4-三唑（DNMT），这是 TNT 炸药的替代物。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
flash_point_f
17.6 °F - closed cup
flash_point_c
-8 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β, β-Disubstituted Enones.
Kawai H, et al.
Angewandte Chemie (International ed. in English), 125(8), 2277-2281 (2013)
A safe and scalable process for the synthesis of melt-cast explosive 1-methyl-3, 5-dinitro-1H-1, 2, 4-triazole.
Luo J, et al.
Chemistry of Heterocyclic Compounds, 53(6-7), 714-718 (2017)
R L Nelson et al.
American journal of surgery, 172(1), 85-88 (1996-07-01)
Selenium (SE) has been inversely associated with colon cancer risk. Two potential mechanisms of this effect were examined in a rodent short-term carcinogenesis assay: whether dietary SE deficiency altered the initiation aspect of carcinogenesis in the colon, and whether SE
M Gamberini et al.
Carcinogenesis, 19(1), 147-155 (1998-02-24)
Several hydrazine derivatives (HD) tested so far have pharmacological activities, but many also have toxic side effects, including carcinogenesis. Their toxicity has been ascribed to carbocations (via formation of azoxy intermediates), alkyl radicals or reactive oxygen species. Cytotoxicity and transformation
C P Siegers et al.
Cancer letters, 65(3), 245-249 (1992-08-31)
Iron-enriched diets caused an increase of tumor rate in two models of dimethylhydrazine(DMH)-induced colon tumorigenesis in mice. The effect was independent of the time the iron-diet was fed, i.e. during DMH-treatment or following the DMH-treatment period. The increase of tumor
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