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Merck
CN

M46845

Sigma-Aldrich

2-甲基呋喃

contains 200-400 BHT as stabilizer, 99%

别名:

邻甲呋喃

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About This Item

经验公式(希尔记法):
C5H6O
CAS号:
分子量:
82.10
Beilstein:
103733
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

2.8 (vs air)

质量水平

蒸汽压

139 mmHg ( 20 °C)
561 mmHg ( 55 °C)

检测方案

99%

形式

liquid

包含

200-400 BHT as stabilizer

折射率

n20/D 1.433 (lit.)

bp

63-66 °C (lit.)

密度

0.91 g/mL at 25 °C (lit.)

SMILES字符串

Cc1ccco1

InChI

1S/C5H6O/c1-5-3-2-4-6-5/h2-4H,1H3

InChI key

VQKFNUFAXTZWDK-UHFFFAOYSA-N

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一般描述

取代呋喃 2-甲基呋喃被认为是内燃机的潜在替代燃料。对其微波谱进行了分析。碳源在不同反应条件下合成 2-MF 已有报道。

应用

2-甲基呋喃可用于通过与马来酸酐的 Diels-Alder 反应合成 外-顺 -1-甲基-7-氧杂双环 [2.2.1] 庚烯-2,3-二羧酸酐。

象形图

FlameSkull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

WGK

WGK 1

闪点(°F)

-7.6 °F

闪点(°C)

-22 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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V Ravindranath et al.
Toxicology and applied pharmacology, 85(1), 78-91 (1986-08-01)
Administration of a single ip dose of 2-methylfuran (2-MF) to male Sprague-Dawley rats at a dose of 100 mg/kg produced centrilobular necrosis of the liver and bronchial injury of the lung, the severity of the lesions increasing with increasing doses
Guangyi Li et al.
ChemSusChem, 5(10), 1958-1966 (2012-08-22)
Hydroxyalkylation-alkylation (HAA) coupled with hydrodeoxygenation is a promising route for the synthesis of renewable high-quality diesel or jet fuel. In this work, a series of solid-acid catalysts were firstly used for HAA between lignocellulose-derived furan and carbonyl compounds. Among the
Renewable production of phthalic anhydride from biomass-derived furan and maleic anhydride.
Mahmoud E, et al.
Green Chemistry, 16(1), 167-175 (2014)
Combustion performance and emissions of 2-methylfuran diesel blends in a diesel engine.
Xiao H, et al.
Fuel: The Science and Technology of Fuel and Energy, 175, 157-163 (2016)
Microwave Spectrum of 2-Methylfuran.
Niorrs WG and Krisher LC.
J. Chem. Phys. , 51, 403-406 (1969)

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