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检测方案
98%
折射率
n20/D 1.494 (lit.)
bp
199-200 °C (lit.)
密度
0.971 g/mL at 25 °C (lit.)
SMILES字符串
CC1=CC(=O)CCC1
InChI
1S/C7H10O/c1-6-3-2-4-7(8)5-6/h5H,2-4H2,1H3
InChI key
IITQJMYAYSNIMI-UHFFFAOYSA-N
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应用
3-Methyl-2-cyclohexenone is an insect sex pheromone of the Douglas-fir beetle. It can be used as a starting material:
- In the total synthesis of (−)-ar-tenuifolene, a naturally occurring aromatic sesquiterpene.
- To synthesize an organic building block 2-trimethylsilyl-3-methyl-cyclohexenone.
- In the total synthesis of natural diterpenoids (+)-taiwaniaquinone H and (+)-dichroanone.
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral
WGK
WGK 3
闪点(°F)
154.4 °F
闪点(°C)
68 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Cyclic α-Acylvinyl Anionic Synthons: A Novel Synthesis of 2-Trimethylsilyl-3-methyl-cyclohexenone by the Wurtz-Fittig Coupling Reaction
Synthetic Communications, 39(5), 875-879 (2009)
Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H
Tetrahedron Letters, 55(43), 5960-5962 (2014)
Catalytic enantioselective total synthesis of (−)-ar-Tenuifolene
Tetrahedron Letters, 61(20), 151850-151850 (2020)
Aldrichimica Acta, 16, 41-41 (1983)
Chembiochem : a European journal of chemical biology, 16(3), 440-445 (2015-02-03)
(4R,6R)-Actinol can be stereo-selectively synthesized from ketoisophorone by a two-step conversion using a mixture of two enzymes: Candida macedoniensis old yellow enzyme (CmOYE) and Corynebacterium aquaticum (6R)-levodione reductase. However, (4S)-phorenol, an intermediate, accumulates because of the limited substrate range of
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