M3394
6-甲基-2,4-庚二酮
≥98%
别名:
Isovalerylacetone, NSC 42238, NSC 42240, NSC 46469, NSC 94
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关于此项目
线性分子式:
(CH3)2CHCH2COCH2COCH3
化学文摘社编号:
分子量:
142.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-093-6
Beilstein/REAXYS Number:
1751122
MDL number:
产品名称
6-甲基-2,4-庚二酮, ≥98%
InChI key
IGMOYJSFRIASIE-UHFFFAOYSA-N
InChI
1S/C8H14O2/c1-6(2)4-8(10)5-7(3)9/h6H,4-5H2,1-3H3
SMILES string
CC(C)CC(=O)CC(C)=O
assay
≥98%
color
colorless to faint yellow
density
0.92 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
Reactant involved in:
- Cyclocondensation and deacetylation of dibromo(phenylsulfonyl)propene derivatives for synthesis of disubstituted furans
- Synthesis of dual activity effectors of angiotensin II type 1 receptors and peroxisome proliferator-activated receptor-γ
- Addition reactions with 1-alkynes
- Knoevenagel condensation
- Oxidative free radical reactions with 2-amino-1,4-benzoquinones
- Mild oxidative cleavage for synthesis of carboxylic acids
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
138.2 °F - closed cup
flash_point_c
59 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Iwona Łakomska et al.
Materials (Basel, Switzerland), 13(23) (2020-12-02)
Herein, we present dicarboxylate platinum(II) complexes of the general formula [Pt(mal)(DMSO)(L)] and [Pt(CBDC)(DMSO)(L)], where L is dbtp 5,7-ditertbutyl-1,2,4-triazolo[1,5-a]pyrimidine) or ibmtp (7-isobutyl-5-methyl-1,2,4- triazolo[1,5-a]pyrimidine), as prospective prodrugs. The platinum(II) complexes were synthesized in a one-pot reaction between cis-[PtCl2(DMSO)2], silver malonate or silver
Marzena Fandzloch et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 25(1), 109-124 (2019-11-20)
Six novel ruthenium(III) complexes of general formula [RuCl3(L)3] (1,3,5) and [RuCl3(H2O)(L)2] (2,4,6), where L stands for three different triazolopyrimidine-derived ligands, are reported. The compounds have been structurally characterized (IR, EPR, SCXRD), and their magnetic moments have been determined. The single-crystal
Marzena Fandzloch et al.
Journal of inorganic biochemistry, 210, 111072-111072 (2020-06-21)
Five novel rhodium(II) complexes of general formula [Rh2(μ-OOCCH3)4L2], where L is a triazolopyrimidine derivative, in particular dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) for (1), 5,7-diethyl-1,2,4-triazolo[1,5-a]pyrimidine (detp) for (2), 7-isobutyl-5-methyl-1,2,4-triazolo[1,5-a]pyrimidine (ibmtp) for (3), 7-hydroxy-5-methyl-1,2,4-triazolo[1,5-a]pyrimidine (HmtpO) for (4) and 5,7-ditertbutyl-1,2,4-triazolo[1,5-a]pyrimidine (dbtp) for (5) are reported. These
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Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
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