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质量水平
方案
95%
表单
liquid
折射率
n20/D 1.3919 (lit.)
沸点
90-92 °C (lit.)
密度
0.806 g/mL at 20 °C
0.804 g/mL at 25 °C (lit.)
SMILES字符串
[H]C(=O)C(C)CC
InChI
1S/C5H10O/c1-3-5(2)4-6/h4-5H,3H2,1-2H3
InChI key
BYGQBDHUGHBGMD-UHFFFAOYSA-N
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应用
2-甲基丁醛可用作合成以下物质的反应物:
- 在乙酸铵存在的情况下通过与各种苯乙酮和丙二腈的多组分缩合反应合成的 2-氨基-3-氰基吡啶衍生物。
- 在氢分子存在的情况下通过与二乙胺的铑催化还原胺化反应合成的N,N-二乙基-2-甲基-1-丁胺。
- α-采用三环非离子强路易斯碱与苯乙腈进行缩合反应合成的(2-甲基亚丁基)苯乙腈。
警示用语:
Danger
危险分类
Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
23.0 °F
闪点(°C)
-5 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
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Shintani T, et al.
Tetrahedron Letters, 44(35), 6567-6569 (2003)
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D'Sa Bosco A, et al.
The Journal of Organic Chemistry, 63(12), 3961-3967 (1998)
Rhodium-Catalysed Reductive Amination for the Synthesis of Tertiary Amines
Bianga J, et al.
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Rhodium-Catalysed Reductive Amination for the Synthesis of Tertiary Amines
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Advanced Synthesis & Catalysis, 362(20), 4415-4424 (2020)
C Zscheppank et al.
Analytical and bioanalytical chemistry, 406(26), 6617-6628 (2014-08-26)
A new method for the growth-dependent headspace analysis of bacterial cultures by needle trap (NT)-gas chromatography-mass spectrometry (GC-MS) was established. NTs were used for the first time as enrichment technique for volatile organic compounds (VOCs) in the headspace of laboratory
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