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Merck
CN

M3205

Sigma-Aldrich

2-巯基苯并咪唑

98%

别名:

1,3-二氢-2 H -苯并咪唑-2-硫酮, 2-苯并咪唑硫醇

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About This Item

经验公式(希尔记法):
C7H6N2S
CAS号:
分子量:
150.20
Beilstein:
119867
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

mp

300-304 °C (lit.)

SMILES字符串

S=C1Nc2ccccc2N1

InChI

1S/C7H6N2S/c10-7-8-5-3-1-2-4-6(5)9-7/h1-4H,(H2,8,9,10)

InChI key

YHMYGUUIMTVXNW-UHFFFAOYSA-N

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相关类别

一般描述

2-巯基苯并咪唑能降低金属腐蚀速度,是良好的缓蚀剂。

应用

2-巯基苯并咪唑用于:
  • 与芳香酮反应制备2-苯并咪唑基硫代苯乙酮,这是合成噻唑并[3,2-a]苯并咪唑的关键中间体。
  • 合成 S-芳基化2-巯基苯并咪唑,合成物由与CuI和1,10-菲咯啉形成的取代芳基碘化物进行 S-芳基化反应得到。

象形图

Skull and crossbonesHealth hazard

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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分析证书(COA)

Lot/Batch Number

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S-arylation of mercaptobenzimidazoles using Cu (I) catalysts-experimental and theoretical observations
Sekar R, et al.
Tetrahedron Letters, 52(26), 3347-3352 (2011)
Yuqin Li et al.
Colloids and surfaces. B, Biointerfaces, 104, 311-317 (2013-01-22)
The interaction of 2-mercaptobenzimidazole (MBI) with human serum albumin (HSA) was studied in vitro by equilibrium dialysis under normal physiological conditions. This study used fluorescence, ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared (FT-IR), circular dichroism (CD) and Raman spectroscopy, atomic force
Kazue Sakemi et al.
Archives of toxicology, 76(12), 682-691 (2002-11-27)
2-Mercaptobenzimidazole (MBI), a rubber antioxidant, is known to exhibit potent thyroid toxicity in rats, whereas its methylated derivatives are much less toxic. To characterize this methyl-substituent effect on the thyroid toxicity of MBI, comparative toxicokinetic analyses have been conducted in
D M Manohar et al.
Water research, 36(6), 1609-1619 (2002-05-09)
The 2-mercaptobenzimidazole loaded natural clay was prepared for the removal of Hg(II) from aqueous media. Adsorption of the metal ions from aqueous solution as a function of solution concentration, agitation time, pH, temperature, ionic strength, particle size of the adsorbent
Evaluation of 2-mercaptobenzimidazole as corrosion inhibitor for mild steel in phosphoric acid
Wang L
Corrosion Science, 43(12), 2281-2289 (2001)

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