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Merck
CN
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文件

M31104

Sigma-Aldrich

α-甲基苄胺

99%

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别名:
(±)-α-甲基苄胺, (±)-1-苯乙胺
线性分子式:
C6H5CH(CH3)NH2
CAS号:
618-36-0
分子量:
121.18
Beilstein:
636127
EC 号:
210-545-8
MDL编号:
MFCD00008069
UNSPSC代码:
12352100
PubChem化学物质编号:
24896793
NACRES:
NA.22

检测方案

99%

形式

liquid

折射率

n20/D 1.526 (lit.)

bp

185 °C/756 mmHg (lit.)

密度

0.94 g/mL at 25 °C (lit.)

SMILES字符串

CC(N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3

InChI key

RQEUFEKYXDPUSK-UHFFFAOYSA-N

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相关类别

一般描述

α-甲基苄胺是一种氮源，被广泛用作研究伯胺化学酶动力学拆分的一种代表性底物。

应用

α-甲基苄胺可通过与外消旋双酚衍生物进行反应，用作合成二氢-5H-二苯并[c，e]氮杂环丙烷盐的反应物。
它可用于合成 o-氟苄胺。

象形图

CorrosionExclamation mark
GHS05,GHS07

警示用语：

Danger

危险声明

H302 + H312,H314

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

分析证书(COA)

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Chemoenzymatic dynamic kinetic resolution of primary amines.
Paetzold, Jens and Backvall, Jan E
Journal of the American Chemical Society, 127(50), 17620-17621 (2005)
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Whole-cell biocatalysis based on metabolically active baker's yeast with engineered transamination activity can be used to generate molecules carrying a chiral amine moiety. A prerequisite is though to express efficient ω-transaminases and to reach sufficient intracellular precursor levels. Herein, the
Boyeong Kang et al.
Scientific reports, 7(1), 4786-4786 (2017-07-08)
The energy flow during natural photosynthesis is controlled by maintaining the spatial arrangement of pigments, employing helices as scaffolds. In this study, we have developed porphyrin-peptoid (pigment-helix) conjugates (PPCs) that can modulate the donor-acceptor energy transfer efficiency with exceptional precision
Kinetic resolution of ??methylbenzylamine with o?transaminase screened from soil microorganisms: Application of a biphasic system to overcome product inhibition.
Shin, Jong-Shik and Kim, Byung-Gee
Biotechnology and Bioengineering, 55(2), 348-358 (1997)
Jan Dines Knudsen et al.
Microbial cell factories, 15, 37-37 (2016-02-18)
Saccharomyces cerevisiae can be engineered to perform a multitude of different chemical reactions that are not programmed in its original genetic code. It has a large potential to function as whole-cell biocatalyst for one-pot multistep synthesis of various organic molecules
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