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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.414 (lit.)
沸点
140 °C (lit.)
密度
0.928 g/mL at 25 °C (lit.)
SMILES字符串
CNCC(OC)OC
InChI
1S/C5H13NO2/c1-6-4-5(7-2)8-3/h5-6H,4H2,1-3H3
InChI key
HUMIEJNVCICTPJ-UHFFFAOYSA-N
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应用
(Methylamino)acetaldehyde dimethyl acetal can be used as a reactant to synthesize:
- Aza[3.3.2] cyclazines by reacting with 5-methyloxazolo[3,2-a]pyridinium salts via synthesis of functionalized 5-aminoindolizines intermediates.
- N-(2,2-Dimethoxyethyl)-N-methyl-3,4-dimethoxyphenylglycine by Petasis reaction with glyoxylic acid and 3,4-dimethoxyphenylboronic acid.
- Substituted imidazoles via copper-catalyzed reaction with various nitriles.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
84.2 °F
闪点(°C)
29 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Expedient synthesis of substituted imidazoles from nitriles
Frutos RP, et al.
Tetrahedron Letters, 46(48), 8369-8372 (2005)
Rearrangement of oxazolo [3, 2-a] pyridines as an approach of synthesizing aza [3.3. 2] cyclazines
Babaev EV, et al.
Chemistry of Heterocyclic Compounds, 51(3), 269-274 (2015)
A concise synthesis of tetrahydroisoquinoline-1-carboxylic acids using a Petasis reaction and Pomeranz-Fritsch-Bobbitt cyclization sequence
Chrzanowska M, et al.
Tetrahedron, 68(14), 3092-3097 (2012)
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