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蒸汽密度
4 (vs air)
质量水平
蒸汽压
<1 mmHg ( 20 °C)
检测方案
99%
形式
liquid
expl. lim.
6.9 %
折射率
n20/D 1.423 (lit.)
bp
166 °C (lit.)
密度
0.931 g/mL at 25 °C (lit.)
SMILES字符串
CC(=O)CC(C)(C)O
InChI
1S/C6H12O2/c1-5(7)4-6(2,3)8/h8H,4H2,1-3H3
InChI key
SWXVUIWOUIDPGS-UHFFFAOYSA-N
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一般描述
4-羟基-4-甲基-2-戊酮通常作为溶剂在各种工业中使用，包括油漆、涂料、胶粘剂和印刷油墨。
应用
4-羟基-4-甲基-2-戊酮可用于合成以下物质：
也可作为络合剂，通过与金属盐(MX)和氰基金属化物反应合成双金属氰化物(DMC)催化剂。
- 二醇单酯，通过串联醇醛转移Tischtschenko反应与醛类反应，以三甲基铝作为催化剂。
- 醇醛转移产物，例如β-羟基酮，通过与各种醛类反应，以L-脯氨酸作为催化剂。
- 单-α-芳化酮和酯类，分别与芳基卤化物和芳基三氟化物发生Pd催化反应。
也可作为络合剂，通过与金属盐(MX)和氰基金属化物反应合成双金属氰化物(DMC)催化剂。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
C-C Activation by Retro-Aldol Reaction of Two ?-Hydroxy Carbonyl Compounds: Synergy with Pd-Catalyzed Cross-Coupling To Access Mono-?-arylated Ketones and Esters
Zhang SL and Yu ZL
The Journal of Organic Chemistry, 81(1), 57-65 (2015)
M Kitulagodage et al.
Ecotoxicology and environmental safety, 71(2), 597-600 (2007-12-25)
Fipronil, a phenyl pyrazole pesticide, is aerially applied in eastern Australia to control locust outbreaks, usually as "Adonis 3UL Insecticide" (BASF), an ultra low (UL) volume formulation containing 0.3% active pesticide. We tested the toxicities of technical-grade fipronil, the Adonis
Self-assembly of tin oxide nanoparticles: localized percolating network formation in polymer matrix.
Atsumi Wakabayashi et al.
Langmuir : the ACS journal of surfaces and colloids, 22(22), 9260-9263 (2006-10-18)
A novel method to prepare transparent antistatic films by trapping nanoparticles in thin surface layers is proposed, and high performance of the product is demonstrated. Coating solutions consisting of surface-active antimony-doped tin oxide (ATO) nanoparticles, an organic solvent mixture of
S Chandrasekhar et al.
Chemical communications (Cambridge, England), (21)(21), 2450-2451 (2004-10-30)
We demonstrate for the first time, L-proline as a chiral catalyst for transfer aldol reaction between aldehydes and diacetone alcohol.
Synthesis of Polycarbonate Polyols by Double-Metal Cyanide Catalyzed Copolymerization of Epoxide with Carbon Dioxide
Lim J, et al.
Journal of Nanoscience and Nanotechnology, 17(10), 7507-7514 (2017)
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