质量水平
检测方案
99%
折射率
n20/D 1.562 (lit.)
bp
114-116 °C/1 mmHg (lit.)
mp
28-34 °C (lit.)
密度
1.243 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
[H]C(=O)c1ccc(CO)o1
InChI
1S/C6H6O3/c7-3-5-1-2-6(4-8)9-5/h1-3,8H,4H2
InChI key
NOEGNKMFWQHSLB-UHFFFAOYSA-N
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应用
5-羟甲基-2-糠醛(HMF)用于下列合成反应:
- 使用钒基磷酸盐催化剂,通过选择性氧化合成2,5-呋喃-二甲醛(FDA)。
- 使用固体酸催化剂,通过醚化反应制得预聚物和抗病毒前体5,5′-氧(双亚甲基)-2-糠醛(OBMF)。
- 使用吡啶-钒基络合物进行有氧氧化,制得二甲酰基呋喃(DFF)。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Selective oxidation of 5-hydroxymethyl-2-furaldehyde to furan-2, 5-dicarboxaldehyde by catalytic systems based on vanadyl phosphate.
Applied Catalysis A: General, 289(2), 197-204 (2005)
Chemicals from biomass: Etherification of 5-hydroxymethyl-2-furfural (HMF) into 5, 5?(oxy-bis (methylene)) bis-2-furfural (OBMF) with solid catalysts.
J. Catal., 275(2), 236-242 (2010)
Chemicals from biomass: Aerobic oxidation of 5-hydroxymethyl-2-furaldehyde into diformylfurane catalyzed by immobilized vanadyl-pyridine complexes on polymeric and organofunctionalized mesoporous supports.
Topics in Catalysis, 52(3), 304-314 (2009)
Physical chemistry chemical physics : PCCP, 14(40), 13914-13917 (2012-09-20)
Mesoporous silica nanoparticles functionalized with both sulfonic acid (HSO(3)) and ionic liquid (ILs) were synthesized and applied as effective and recyclable catalysts for generating 5-hydroxymethylfurfural (HMF) from fructose. For the first time a high HMF yield of 72.5% was achieved
Bioresource technology, 132, 342-350 (2013-02-26)
Acidity modified silver exchanged silicotungstic acid (AgSTA) catalyst was prepared and characterized by X-ray diffraction, FT-IR spectroscopy, Raman spectroscopy, FT-IR pyridine adsorption, SEM imaging, EDX mapping, and antimicrobial activity was also tested. The catalytic activity was evaluated for the dehydration
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