H11602
六甲基磷酰三胺
99%
别名:
HMPA, 三(二甲氨基)氧膦, 六甲基磷酸三胺
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线性分子式:
[(CH3)2N]3PO
化学文摘社编号:
分子量:
179.20
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-653-8
Beilstein/REAXYS Number:
1099903
MDL number:
产品名称
六甲基磷酰三胺, 99%
InChI
1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3
InChI key
GNOIPBMMFNIUFM-UHFFFAOYSA-N
SMILES string
CN(C)P(=O)(N(C)C)N(C)C
vapor density
6.18 (vs air)
vapor pressure
0.07 mmHg ( 25 °C)
assay
99%
refractive index
n20/D 1.459 (lit.)
bp
230-232 °C/740 mmHg (lit.)
mp
7 °C (lit.)
density
1.03 g/mL at 25 °C (lit.)
Quality Level
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Application
六甲基磷酰胺可用作以下过程的溶剂：
- 通过与烷基卤化物反应将羧酸盐转化为酯。
- 通过硫醇离子亲核置换未活化的芳基卤化物来合成芳基硫醚。
- 通过高温溶液缩聚将二醛和二胺合成聚甲亚胺（PAZs）。
General description
六甲基磷酰胺是一种极性非质子溶剂。
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
291.2 °F - closed cup
flash_point_c
144 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Controlled/?Living? Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate.
Chen X P, et al.
Macromolecules, 35(11), 4277-4281 (2002)
Optical and structural study of thin film of polyazomethine with triphenylamine unit prepared via spin-coating method.
Palewicz M, et al.
Polymer Bull., 66(1), 65-76 (2011)
Nucleophilic aromatic substitution reactions of unactivated aryl halides with thiolate ions in hexamethylphosphoramide.
Cogolli P, et al.
The Journal of Organic Chemistry, 44(15), 2642-2646 (1979)
Hexamethylphosphoramide
Normant H.
Angewandte Chemie (International Edition in English), 6(12), 1046-1067 (1967)
Drug-HPMA-HuIg conjugates effective against human solid cancer.
Blanka Ríhová et al.
Advances in experimental medicine and biology, 519, 125-143 (2003-04-05)
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