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主要文件

H11602

Sigma-Aldrich

六甲基磷酰三胺

99%

别名:

HMPA, 三(二甲氨基)氧膦, 六甲基磷酸三胺

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30 ML
¥5,619.29

¥5,619.29


国内现货,预计发货时间2025年4月24日详情


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30 ML
¥5,619.29

About This Item

线性分子式:
[(CH3)2N]3PO
CAS号:
分子量:
179.20
Beilstein:
1099903
EC 号:
MDL编号:
UNSPSC代码:
12352111
PubChem化学物质编号:
NACRES:
NA.22

¥5,619.29


国内现货,预计发货时间2025年4月24日详情


获取大包装报价

蒸汽密度

6.18 (vs air)

质量水平

蒸汽压

0.07 mmHg ( 25 °C)

方案

99%

折射率

n20/D 1.459 (lit.)

沸点

230-232 °C/740 mmHg (lit.)

mp

7 °C (lit.)

密度

1.03 g/mL at 25 °C (lit.)

SMILES字符串

CN(C)P(=O)(N(C)C)N(C)C

InChI

1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3

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50208U50197U50193U
matrix

octadecyl

matrix

octadecyl

matrix

sulphonic acid

matrix

tetramethyl ammonium

separation technique

reversed phase

separation technique

reversed phase

separation technique

cation exchange

separation technique

anion exchange

matrix active group

C18 (octadecyl) phase

matrix active group

C18 (octadecyl) phase

matrix active group

sulfonic acid phase

matrix active group

ammonium ion, quaternary phase

technique(s)

HPLC: suitable

technique(s)

HPLC: suitable

technique(s)

HPLC: suitable

technique(s)

HPLC: suitable

pore size

85 Å

pore size

85 Å

pore size

85 Å

pore size

85 Å

一般描述

六甲基磷酰胺是一种极性非质子溶剂。[1]

应用

六甲基磷酰胺可用作以下过程的溶剂:
  • 通过与烷基卤化物反应将羧酸盐转化为酯。[2]
  • 通过硫醇离子亲核置换未活化的芳基卤化物来合成芳基硫醚。[3]
  • 通过高温溶液缩聚将二醛和二胺合成聚甲亚胺(PAZs)。[4]

象形图

Health hazardCorrosion

警示用语:

Danger

危险声明

危险分类

Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

291.2 °F - closed cup

闪点(°C)

144 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

  • 技术规格说明书

  • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number

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    Hexamethylphosphoramide
    Normant H.
    Angewandte Chemie (International Edition in English), 6(12), 1046-1067 (1967)
    Controlled/?Living? Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate.
    Chen X P, et al.
    Macromolecules, 35(11), 4277-4281 (2002)
    Optical and structural study of thin film of polyazomethine with triphenylamine unit prepared via spin-coating method.
    Palewicz M, et al.
    Polymer Bull., 66(1), 65-76 (2011)
    Nucleophilic aromatic substitution reactions of unactivated aryl halides with thiolate ions in hexamethylphosphoramide.
    Cogolli P, et al.
    The Journal of Organic Chemistry, 44(15), 2642-2646 (1979)
    Amin Jafari et al.
    Materials (Basel, Switzerland), 13(4) (2020-02-23)
    As a promising strategy for the treatment of various diseases, gene therapy has attracted increasing attention over the past decade. Among various gene delivery approaches, non-viral vectors made of synthetic biomaterials have shown significant potential. Due to their synthetic nature

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