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线性分子式:
[(CH3)2N]3PO
化学文摘社编号:
分子量:
179.20
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-653-8
Beilstein/REAXYS Number:
1099903
MDL number:
产品名称
六甲基磷酰三胺, 99%
InChI
1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3
InChI key
GNOIPBMMFNIUFM-UHFFFAOYSA-N
SMILES string
CN(C)P(=O)(N(C)C)N(C)C
vapor density
6.18 (vs air)
vapor pressure
0.07 mmHg ( 25 °C)
assay
99%
refractive index
n20/D 1.459 (lit.)
bp
230-232 °C/740 mmHg (lit.)
mp
7 °C (lit.)
density
1.03 g/mL at 25 °C (lit.)
Quality Level
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Application
六甲基磷酰胺可用作以下过程的溶剂:
- 通过与烷基卤化物反应将羧酸盐转化为酯。
- 通过硫醇离子亲核置换未活化的芳基卤化物来合成芳基硫醚。
- 通过高温溶液缩聚将二醛和二胺合成聚甲亚胺(PAZs)。
General description
六甲基磷酰胺是一种极性非质子溶剂。
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
291.2 °F - closed cup
flash_point_c
144 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Nucleophilic aromatic substitution reactions of unactivated aryl halides with thiolate ions in hexamethylphosphoramide.
Cogolli P, et al.
The Journal of Organic Chemistry, 44(15), 2642-2646 (1979)
Controlled/?Living? Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate.
Chen X P, et al.
Macromolecules, 35(11), 4277-4281 (2002)
Optical and structural study of thin film of polyazomethine with triphenylamine unit prepared via spin-coating method.
Palewicz M, et al.
Polymer Bull., 66(1), 65-76 (2011)
Hexamethylphosphoramide
Normant H.
Angewandte Chemie (International Edition in English), 6(12), 1046-1067 (1967)
Bahar Zarabi et al.
Pharmaceutical research, 26(5), 1121-1129 (2009-01-23)
To evaluate the tumor targeting potential of N-(2-hydroxypropyl)methacrylamide (HPMA) copolymer-gadolinium(Gd)-RGDfK conjugates by magnetic resonance (MR) T1-mapping. HPMA copolymers with and without RGDfK were synthesized to incorporate side chains for Gd chelation. The conjugates were characterized by their side-chain contents and
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