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Merck
CN

G7305

甘脲

97%

别名:

NSC 2765, 乙炔脲

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关于此项目

经验公式(希尔记法):
C4H6N4O2
化学文摘社编号:
分子量:
142.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-821-5
Beilstein/REAXYS Number:
128826
MDL number:
Assay:
97%
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InChI

1S/C4H6N4O2/c9-3-5-1-2(7-3)8-4(10)6-1/h1-2H,(H2,5,7,9)(H2,6,8,10)

InChI key

VPVSTMAPERLKKM-UHFFFAOYSA-N

SMILES string

O=C1NC2NC(=O)NC2N1

assay

97%

mp

>300 °C (lit.)

Quality Level

Application

参与合成以下物质的反应物:
  • 甘草六聚体和单官能团瓜环[6]衍生物
  • 三氯异氰尿酸中的N-氯化合物
  • 甘草三聚体

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

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Dariush Ajami et al.
Nature chemistry, 1(1), 87-90 (2009-04-01)
Simple alkanes feature fully extended conformations as their lowest-energy shapes but can assume coiled, compressed conformations in small spaces. A series of normal alkanes, C(16) to C(19), were encapsulated in self-assembled, hydrogen-bonded complexes. Coiling of the longer alkanes was observed
Dariush Ajami et al.
Topics in current chemistry, 319, 57-78 (2011-11-04)
Synthetic receptors that surround their target molecules - self assembled capsules and deep cavitands - have emerged as the most realistic models of enzymes active sites. They were introduced to study the behaviour of molecules isolated in small spaces and
Longer guests drive the reversible assembly of hyperextended capsules.
Dariush Ajami et al.
Angewandte Chemie (International ed. in English), 46(48), 9283-9286 (2007-11-08)
Toshiaki Taira et al.
Journal of the American Chemical Society, 134(29), 11971-11973 (2012-07-07)
Encapsulation of ion pairs in small spaces that are isolated from the medium is expected to result in amplified interactions between the ions. Yet, sequestration of ion pairs in self-assembled capsules is complicated by competition of the acids and bases
Neng-Fang She et al.
Journal of the American Chemical Society, 131(33), 11695-11697 (2009-09-03)
A programmed assembly process produces rhombic grid networks from compounds L1-L4 in the crystal by pi-pi stacking interactions that generate a bimolecular grid synthon, which undergoes further NH...N hydrogen-bond-mediated assembly.

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