F6129
柠檬酸铁 (III)
technical grade
别名:
柠檬酸铁, 柠檬酸铁（III）, 柠檬酸铁（III）水合物
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关于此项目
经验公式（希尔记法）:
C6H5FeO7
化学文摘社编号:
分子量:
244.94
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
222-536-6
MDL number:
Grade:
technical grade
Form:
powder
InChI key
NPFOYSMITVOQOS-UHFFFAOYSA-K
InChI
1S/C6H8O7.Fe/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);/q;+3/p-3
SMILES string
OC12CC(=O)O[Fe](OC(=O)C1)OC2=O
grade
technical grade
form
powder
composition
Fe, 16.5-18.5%
reaction suitability
core: iron
technique(s)
cell culture | mammalian: suitable
Quality Level
General description
柠檬酸铁（技术级）为棕色至暗橙色粉末。可溶于水，但不溶于大部分有机物，包括乙醇。该粉末对光敏感；同很多羧酸铁一样，蓝光还原柠檬酸铁，形成Fe2+离子，同时氧化羧基生成二氧化碳。柠檬酸铁在460 °C下热分解为α-Fe2O3。
Application
柠檬酸铁可作为前体合成各种含铁物质。常用于水热法制备Fe3O4 纳米粒子或Fe3O4-纳米复合材料，热解和溶胶-凝胶法制备Fe2O3材料。柠檬酸铁的高水溶性和无机低溶性十分适合用于溶胶-凝胶技术。柠檬酸铁作为重要前体合成掺铁和含铁金属氧化物，用于锂离子电池正极。
还可降解四环素用于污水处理。
还可降解四环素用于污水处理。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
P Senthil Kumar et al.
ACS omega, 3(3), 3036-3044 (2018-07-20)
Pristine trivanadate (LiV3O8) and doped lithium trivanadate (LiV3-x M x O8, M = Zn/Co/Fe/Sn/Ti/Zr/Nb/Mo, x = 0.01/0.05/0.1 M) compounds were prepared by a simple reflux method in the presence of the polymer, Pluronic P123, as the chelating agent. For comparison
Jianguo Guan et al.
Chemical communications (Cambridge, England), 46(35), 6605-6607 (2010-08-18)
We present a simple and effective heterogeneous contraction method to fabricate hollow spheres with controllable interior structures (ranging from solid, simple hollow to core-in-hollow-wall, double-wall hollow and core-in-double-hollow-wall spheres) by a non-equilibrium heat-treatment process of gel precursors with a high
Tatsuya Fukushima et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(42), 16829-16834 (2012-10-03)
Citrate is a common biomolecule that chelates Fe(III). Many bacteria and plants use ferric citrate to fulfill their nutritional requirement for iron. Only the Escherichia coli ferric citrate outer-membrane transport protein FecA has been characterized; little is known about other
Petra Vukosav et al.
Analytica chimica acta, 745, 85-91 (2012-09-04)
A detailed study of iron (III)-citrate speciation in aqueous solution (θ=25°C, I(c)=0.7 mol L(-1)) was carried out by voltammetric and UV-vis spectrophotometric measurements and the obtained data were used for reconciled characterization of iron (III)-citrate complexes. Four different redox processes
Marcus J Edwards et al.
Structure (London, England : 1993), 20(7), 1275-1284 (2012-06-12)
Members of the genus Shewanella translocate deca- or undeca-heme cytochromes to the external cell surface thus enabling respiration using extracellular minerals and polynuclear Fe(III) chelates. The high resolution structure of the first undeca-heme outer membrane cytochrome, UndA, reveals a crossed
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