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Merck
CN

F6129

Sigma-Aldrich

柠檬酸铁 (III)

technical grade

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别名:
柠檬酸铁, 柠檬酸铁(III), 柠檬酸铁(III)水合物
经验公式(希尔记法):
C6H5FeO7
CAS号:
分子量:
244.94
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

等级

technical grade

质量水平

形式

powder

组成

Fe, 16.5-18.5%

技术

cell culture | mammalian: suitable

应用

battery manufacturing

SMILES字符串

OC12CC(=O)O[Fe](OC(=O)C1)OC2=O

InChI

1S/C6H8O7.Fe/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);/q;+3/p-3

InChI key

NPFOYSMITVOQOS-UHFFFAOYSA-K

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一般描述

柠檬酸铁(技术级)为棕色至暗橙色粉末。可溶于水,但不溶于大部分有机物,包括乙醇。该粉末对光敏感;同很多羧酸铁一样,蓝光还原柠檬酸铁,形成Fe2+离子,同时氧化羧基生成二氧化碳。柠檬酸铁在460 °C下热分解为α-Fe2O3

应用

柠檬酸铁可作为前体合成各种含铁物质。常用于水热法制备Fe3O4 纳米粒子或Fe3O4-纳米复合材料,热解和溶胶-凝胶法制备Fe2O3材料。柠檬酸铁的高水溶性和无机低溶性十分适合用于溶胶-凝胶技术。柠檬酸铁作为重要前体合成掺铁和含铁金属氧化物,用于锂离子电池正极。

还可降解四环素用于污水处理。

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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P Senthil Kumar et al.
ACS omega, 3(3), 3036-3044 (2018-07-20)
Pristine trivanadate (LiV3O8) and doped lithium trivanadate (LiV3-x M x O8, M = Zn/Co/Fe/Sn/Ti/Zr/Nb/Mo, x = 0.01/0.05/0.1 M) compounds were prepared by a simple reflux method in the presence of the polymer, Pluronic P123, as the chelating agent. For comparison
Jianguo Guan et al.
Chemical communications (Cambridge, England), 46(35), 6605-6607 (2010-08-18)
We present a simple and effective heterogeneous contraction method to fabricate hollow spheres with controllable interior structures (ranging from solid, simple hollow to core-in-hollow-wall, double-wall hollow and core-in-double-hollow-wall spheres) by a non-equilibrium heat-treatment process of gel precursors with a high
Tatsuya Fukushima et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(42), 16829-16834 (2012-10-03)
Citrate is a common biomolecule that chelates Fe(III). Many bacteria and plants use ferric citrate to fulfill their nutritional requirement for iron. Only the Escherichia coli ferric citrate outer-membrane transport protein FecA has been characterized; little is known about other
Marcus J Edwards et al.
Structure (London, England : 1993), 20(7), 1275-1284 (2012-06-12)
Members of the genus Shewanella translocate deca- or undeca-heme cytochromes to the external cell surface thus enabling respiration using extracellular minerals and polynuclear Fe(III) chelates. The high resolution structure of the first undeca-heme outer membrane cytochrome, UndA, reveals a crossed
Miriam A Rosenbaum et al.
PloS one, 7(2), e30827-e30827 (2012-02-10)
Shewanella oneidensis is a target of extensive research in the fields of bioelectrochemical systems and bioremediation because of its versatile metabolic capabilities, especially with regard to respiration with extracellular electron acceptors. The physiological activity of S. oneidensis to respire at

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