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Merck
CN

F6129

柠檬酸铁 (III)

technical grade

别名:

柠檬酸铁, 柠檬酸铁(III), 柠檬酸铁(III)水合物

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关于此项目

经验公式(希尔记法):
C6H5FeO7
化学文摘社编号:
分子量:
244.94
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
222-536-6
MDL number:
Grade:
technical grade
Form:
powder
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产品名称

柠檬酸铁 (III), technical grade

InChI key

NPFOYSMITVOQOS-UHFFFAOYSA-K

InChI

1S/C6H8O7.Fe/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);/q;+3/p-3

SMILES string

OC12CC(=O)O[Fe](OC(=O)C1)OC2=O

grade

technical grade

form

powder

composition

Fe, 16.5-18.5%

reaction suitability

core: iron

technique(s)

cell culture | mammalian: suitable

Quality Level

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Application

柠檬酸铁可作为前体合成各种含铁物质。常用于水热法制备Fe3O4 纳米粒子或Fe3O4-纳米复合材料,热解和溶胶-凝胶法制备Fe2O3材料。柠檬酸铁的高水溶性和无机低溶性十分适合用于溶胶-凝胶技术。柠檬酸铁作为重要前体合成掺铁和含铁金属氧化物,用于锂离子电池正极。

还可降解四环素用于污水处理。

General description

柠檬酸铁(技术级)为棕色至暗橙色粉末。可溶于水,但不溶于大部分有机物,包括乙醇。该粉末对光敏感;同很多羧酸铁一样,蓝光还原柠檬酸铁,形成Fe2+离子,同时氧化羧基生成二氧化碳。柠檬酸铁在460 °C下热分解为α-Fe2O3

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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分析证书(COA)

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P Senthil Kumar et al.
ACS omega, 3(3), 3036-3044 (2018-07-20)
Pristine trivanadate (LiV3O8) and doped lithium trivanadate (LiV3-x M x O8, M = Zn/Co/Fe/Sn/Ti/Zr/Nb/Mo, x = 0.01/0.05/0.1 M) compounds were prepared by a simple reflux method in the presence of the polymer, Pluronic P123, as the chelating agent. For comparison
Jianguo Guan et al.
Chemical communications (Cambridge, England), 46(35), 6605-6607 (2010-08-18)
We present a simple and effective heterogeneous contraction method to fabricate hollow spheres with controllable interior structures (ranging from solid, simple hollow to core-in-hollow-wall, double-wall hollow and core-in-double-hollow-wall spheres) by a non-equilibrium heat-treatment process of gel precursors with a high
Jessica A Smith et al.
Applied and environmental microbiology, 79(3), 901-907 (2012-11-28)
Geobacter species are important Fe(III) reducers in a diversity of soils and sediments. Mechanisms for Fe(III) oxide reduction have been studied in detail in Geobacter sulfurreducens, but a number of the most thoroughly studied outer surface components of G. sulfurreducens
Hiroaki Ito et al.
The journal of physical chemistry. A, 115(21), 5371-5379 (2011-05-13)
The kinetics of ligand exchange between ferric citrate and desferrioxamine B (DFB) was investigated at pH 8.0 and high citrate/Fe molar ratios (500-5000) with particular attention given to understanding the precise mechanism of ligand exchange. Ferric citrate complexes present in
Marvin Sinsakul et al.
Nephron. Clinical practice, 121(1-2), c25-c29 (2012-10-19)
A phase II open-label study was conducted in hemodialysis patients evaluating the short-term safety, tolerability, and iron absorption with ferric citrate when used as a phosphate binder. Enrollment occurred in two periods. Period 1 recruited patients taking 6-15 pills/day of

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