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Merck
CN

F1506

Sigma-Aldrich

9-芴酮

98%

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别名:
9H-Fluorene-9-one, Fluoren-9-one (8CI)
经验公式(希尔记法):
C13H8O
CAS号:
分子量:
180.20
Beilstein:
1636531
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

bp

342 °C (lit.)

mp

80-83 °C (lit.)

SMILES字符串

O=C1c2ccccc2-c3ccccc13

InChI

1S/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H

InChI key

YLQWCDOCJODRMT-UHFFFAOYSA-N

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应用

9-芴酮已被广泛用作合成各种有机电子材料的前体。一些一般的例子是:
  • 蓝色和绿色磷光有机发光二极管(PHOLEDs)的主体的合成。
  • 芴基分子马达的合成。
  • 开壳 Chichibabin 碳氢化合物作为潜在的有机自旋电子材料的合成。
  • 通过 1,2-二(1-萘基)乙烷的光敏化作用,它也可以作为一种敏化剂来形成二萘品苯。

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

预防措施声明

危险分类

Aquatic Chronic 2 - Eye Irrit. 2

WGK

WGK 3

闪点(°F)

325.4 °F

闪点(°C)

163 °C

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Novel carbazole/fluorene hybrids: Host materials for blue phosphorescent OLEDs.
Shih P I, et al.
Organic Letters, 8(13), 2799-2802 (2006)
Stable Tetrabenzo-Chichibabin?s hydrocarbons: tunable ground state and unusual transition between their closed-shell and open-shell resonance forms.
Zeng Z, et al.
Journal of the American Chemical Society, 134(35), 14513-14525 (2012)
Facile synthesis of picene from 1, 2-di (1-naphthyl) ethane by 9-fluorenone-sensitized photolysis.
Okamoto H, et al.
Organic Letters, 13(10), 2758-2761 (2011)
Yufang Liu et al.
Journal of computational chemistry, 30(16), 2723-2727 (2009-04-29)
The geometric structures and infrared (IR) spectra in the electronically excited state of a novel doubly hydrogen-bonded complex formed by fluorenone and alcohols, which has been observed by IR spectra in experimental study, are investigated by the time-dependent density functional
Tuning the rotation rate of light-driven molecular motors.
Bauer J, et al.
The Journal of Organic Chemistry, 79(10), 4446-4455 (2014)

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