E51406
1-乙炔基-1-环己醇
≥99%
别名:
1-乙炔基-1-羟基环己烷, 1-乙炔基环己醛, 1-乙炔环己醇, 1-羟基-1-乙炔基环己烷, （1-羟基环己基）乙炔
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关于此项目
线性分子式:
HC≡CC6H10OH
化学文摘社编号:
分子量:
124.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-100-9
Beilstein/REAXYS Number:
471404
MDL number:
产品名称
1-乙炔基-1-环己醇, ≥99%
InChI key
QYLFHLNFIHBCPR-UHFFFAOYSA-N
InChI
1S/C8H12O/c1-2-8(9)6-4-3-5-7-8/h1,9H,3-7H2
SMILES string
OC1(CCCCC1)C#C
vapor pressure
<1 mmHg ( 20 °C)
assay
≥99%
bp
180 °C (lit.)
mp
30-33 °C (lit.)
density
0.967 g/mL at 25 °C (lit.)
Quality Level
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Application
1-乙炔基-1-环己醇 (ECHO) 在常温下可在催化量的氯化钌存在下发生乙酰化反应。可用于合成对组织蛋白酶 B 具有强效抑制活性的新型有机碲 (IV) 化合物。过渡金属催化剂引发的 ECHO 聚合反应导致了 ECHO 聚合体的形成。它也可以通过插入 M-H 键与转换金属氢化物反应形成乙烯基衍生物。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Tellurium-based cysteine protease inhibitors: evaluation of novel organotellurium (IV) compounds as inhibitors of human cathepsin B.
Cunha RL
Bioorganic & Medicinal Chemistry Letters, 15(3), 755-760 (2005)
Ruthenium (III) chloride catalyzed acylation of alcohols, phenols, thiols, and amines.
De SK
Tetrahedron Letters, 45(14), 2919-2922 (2004)
Reactions of RuHCl (CO)(PiPr3) 2 with Alkyn-1-ols: Synthesis of Ruthenium (II) Hydroxyvinyl and Vinylcarbene Complexes.
Esteruelas MA
Organometallics, 13(11), 4258-4265 (1994)
Polymerization of 1-Ethynyl-1-cyclohexanol by Transition Metal Catalysts.
Gal YS
J. Macromol. Sci., Pure Appl. Chem., 31(6), 703-714 (1994)
Artem Kovalenko et al.
Soft matter, 13(25), 4526-4532 (2017-06-08)
In this paper, we investigate the factors affecting the sound speed in air-filled macroporous polymer materials at ultrasound frequencies. Due to the presence of large proportion of gas, these porous materials present high compressibility and, as a consequence, low sound
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