所有图片(2)
别名:
(1-Hydroxycyclohexyl)acetylene, (1-Hydroxycyclohexyl)ethyne, 1-Ethynyl-1-hydroxycyclohexane, 1-Ethynylcyclohexanal, 1-Ethynylcyclohexanol, 1-Hydroxy-1-ethynylcyclohexane, Ethynylcyclohexanol
线性分子式:
HC≡CC6H10OH
CAS号:
分子量:
124.18
Beilstein:
471404
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽压
<1 mmHg ( 20 °C)
质量水平
检测方案
≥99%
bp
180 °C (lit.)
mp
30-33 °C (lit.)
密度
0.967 g/mL at 25 °C (lit.)
SMILES字符串
OC1(CCCCC1)C#C
InChI
1S/C8H12O/c1-2-8(9)6-4-3-5-7-8/h1,9H,3-7H2
InChI key
QYLFHLNFIHBCPR-UHFFFAOYSA-N
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应用
1-乙炔基-1-环己醇 (ECHO) 在常温下可在催化量的氯化钌存在下发生乙酰化反应。可用于合成对组织蛋白酶 B 具有强效抑制活性的新型有机碲 (IV) 化合物。过渡金属催化剂引发的 ECHO 聚合反应导致了 ECHO 聚合体的形成。它也可以通过插入 M-H 键与转换金属氢化物反应形成乙烯基衍生物。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
WGK
WGK 1
闪点(°F)
163.4 °F
闪点(°C)
73 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Polymerization of 1-Ethynyl-1-cyclohexanol by Transition Metal Catalysts.
Gal YS
J. Macromol. Sci., Pure Appl. Chem., 31(6), 703-714 (1994)
Ruthenium (III) chloride catalyzed acylation of alcohols, phenols, thiols, and amines.
De SK
Tetrahedron Letters, 45(14), 2919-2922 (2004)
Tellurium-based cysteine protease inhibitors: evaluation of novel organotellurium (IV) compounds as inhibitors of human cathepsin B.
Cunha RL
Bioorganic & Medicinal Chemistry Letters, 15(3), 755-760 (2005)
Reactions of RuHCl (CO)(PiPr3) 2 with Alkyn-1-ols: Synthesis of Ruthenium (II) Hydroxyvinyl and Vinylcarbene Complexes.
Esteruelas MA
Organometallics, 13(11), 4258-4265 (1994)
Artem Kovalenko et al.
Soft matter, 13(25), 4526-4532 (2017-06-08)
In this paper, we investigate the factors affecting the sound speed in air-filled macroporous polymer materials at ultrasound frequencies. Due to the presence of large proportion of gas, these porous materials present high compressibility and, as a consequence, low sound
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