推荐产品
质量水平
方案
98%
表单
liquid
反应适用性
reagent type: oxidant
折射率
n20/D 1.416 (lit.)
沸点
135 °C (lit.)
密度
1.222 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(=O)C(Cl)=O
InChI
1S/C4H5ClO3/c1-2-8-4(7)3(5)6/h2H2,1H3
InChI key
OWZFULPEVHKEKS-UHFFFAOYSA-N
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应用
氯氧乙酸乙酯可用于合成：
- α-酮酯。
- 官能化3-吡咯啉-2-酮。
- 取代芳基乙醛酸（通过Friedel-Crafts酰化反应）。
- 取代9,10-菲醌。
- 喹喔啉酮衍生物。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
105.8 °F - closed cup
闪点(°C)
41 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of arylglyoxylic acids and their collision-induced dissociation.
Wadhwa K, et al.
Synthetic Communications, 38(24), 4434-4444 (2008)
Microwave assisted synthesis of novel imidazo [2, 1-b] thiazole derivative attached to quinoxalinones.
Mukherjee C, et al.
Tetrahedron Letters, 53(45), 6008-6014 (2012)
A one-pot synthesis of functionalised 3-pyrolin-2-ones by a four-component reaction between triphenylphosphine, primary amines, dimethyl acetylenedicarboxylate and ethyl chlorooxoacetate.
Anary-Abbasinejad M, et al.
J. Chem. Res. (M), 2007(10), 574-574 (2007)
A Convenient Synthesis of alpha-Keto Esters Using Ethyl 2-Pyridyl Oxalate.
Lee, Jae In
J. Korean Chem. Soc., 48(1), 103-103 (2004)
An Efficient and Scalable Synthesis of Substituted Phenanthrenequinones by Intramolecular Friedel- Crafts Reaction of Imidazolides.
Yoshikawa N, et al.
Organic Letters, 9(21), 4103-4106 (2007)
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