质量水平
检测方案
98%
形式
liquid
反应适用性
reagent type: oxidant
折射率
n20/D 1.416 (lit.)
bp
135 °C (lit.)
密度
1.222 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(=O)C(Cl)=O
InChI
1S/C4H5ClO3/c1-2-8-4(7)3(5)6/h2H2,1H3
InChI key
OWZFULPEVHKEKS-UHFFFAOYSA-N
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应用
氯氧乙酸乙酯可用于合成:
- α-酮酯。
- 官能化3-吡咯啉-2-酮。
- 取代芳基乙醛酸(通过Friedel-Crafts酰化反应)。
- 取代9,10-菲醌。
- 喹喔啉酮衍生物。
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
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A one-pot synthesis of functionalised 3-pyrolin-2-ones by a four-component reaction between triphenylphosphine, primary amines, dimethyl acetylenedicarboxylate and ethyl chlorooxoacetate.
J. Chem. Res. (M), 2007(10), 574-574 (2007)
An Efficient and Scalable Synthesis of Substituted Phenanthrenequinones by Intramolecular Friedel- Crafts Reaction of Imidazolides.
Organic Letters, 9(21), 4103-4106 (2007)
Dalton transactions (Cambridge, England : 2003), 49(34), 11851-11858 (2020-07-24)
A bimetallic Cu(ii) complex as a novel antitumor chemodynamic therapy agent with glutathione (GSH) depletion properties is successfully synthesized and well characterized. In tumor cells, the Cu2+ ions of the complex are reduced to Cu+ ions by GSH and then
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