E3708
乙硫醇
97%
别名:
C2 硫醇, 硫代乙醇
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关于此项目
线性分子式:
C2H5SH
化学文摘社编号:
分子量:
62.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-837-3
Beilstein/REAXYS Number:
773638
MDL number:
Assay:
97%
Form:
liquid
InChI key
DNJIEGIFACGWOD-UHFFFAOYSA-N
InChI
1S/C2H6S/c1-2-3/h3H,2H2,1H3
SMILES string
CCS
vapor density
2.1 (vs air)
vapor pressure
8.51 psi ( 20 °C)
assay
97%
form
liquid
autoignition temp.
570 °F
expl. lim.
18.2 %
refractive index
n20/D 1.4306 (lit.)
bp
35 °C (lit.)
density
0.839 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
乙硫醇可用作反应物，进行下列合成反应：
- 共轭亲核加成-亲电胺化反应合成带官能团的恶唑烷酮
- C-S与碘苯偶合形成苯乙硫醚
- N-异丙基丙烯酰胺的RAFT聚合中合成链转移剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-49.0 °F - closed cup
flash_point_c
-45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Efficient CuO-Nanoparticle-Catalyzed C-S Cross-Coupling of Thiols with Iodobenzene
Rout L, et al.
Angewandte Chemie (International Edition in English), 119(29), 5679-5682 (2007)
Asymmetric multicomponent domino reactions and highly enantioselective conjugated addition of thiols to ?, ?-unsaturated aldehydes
Marigo M, et al
Journal of the American Chemical Society, 127(45), 15710-15711 (2005)
Direct synthesis of thermally responsive DMA/NIPAM diblock and DMA/NIPAM/DMA triblock copolymers via aqueous, room temperature RAFT polymerization
Convertine AJ, et al.
Macromolecules, 39(5), 1724-1730 (2006)
Nariyasu Mano et al.
Analytical chemistry, 81(22), 9395-9401 (2009-10-23)
The analysis of post-translational phosphorylation is a crucial step in understanding the mechanisms of many physiological events. Numerous approaches for the development of analytical methods aimed at the detection and quantification of phosphorylated proteins by mass spectrometry have been reported
Edmanuel Torres et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 12(5), 999-1009 (2011-03-12)
The translational and orientational potential energy surfaces (PESs) of n-alkanethiols with up to four carbon atoms are studied for (√(3)×√(3))R30° self-assembled monolayers (SAMs). The PESs indicate that methanethiol may form SAM structures that are not accessible for long-chain thiols. The
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