E18425
氰乙酸乙酯
≥98%
别名:
α-氰基乙酸乙酯, 2-氰基乙酸乙酯, 3-乙氧基-3-氧代丙腈, 丙二酸乙酯腈, 氰基乙酸乙酯, 氰基乙酸酯, （乙氧基碳基）乙腈
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关于此项目
线性分子式:
NCCH2COOC2H5
化学文摘社编号:
分子量:
113.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-309-0
Beilstein/REAXYS Number:
605871
MDL number:
产品名称
氰乙酸乙酯, ≥98%
InChI key
ZIUSEGSNTOUIPT-UHFFFAOYSA-N
InChI
1S/C5H7NO2/c1-2-8-5(7)3-4-6/h2-3H2,1H3
SMILES string
CCOC(=O)CC#N
vapor density
3.9 (vs air)
vapor pressure
1 mmHg ( 67.8 °C)
assay
≥98%
form
liquid
refractive index
n20/D 1.418 (lit.)
bp
208-210 °C (lit.)
mp
−22 °C (lit.)
density
1.063 g/mL at 25 °C (lit.)
Quality Level
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Application
氰基乙酸乙酯可用于合成乙醛酸乙酯。通过将氨基嫁接到 NaX和CsNaX 沸石上获得的沸石催化剂，并将其用于研究微反应器中的Knoevenagel 缩合反应。
General description
氰基乙酸乙酯是酯。报道了氰基乙酸乙酯与醛的Knoevenagel 缩合反应。研究人员报道了氰基乙酸乙酯与醛、P2O5、哌啶和氯苯的微波增强Knoevenegal 缩合反应。
氰基乙酸乙酯广泛用作有机合成中的合成砌块，用于生成活性药物成分。
氰基乙酸乙酯广泛用作有机合成中的合成砌块，用于生成活性药物成分。
Packaging
封装在玻璃瓶中
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
230.0 °F
flash_point_c
110 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Electrogenerated bases VII. Novel syntheses of ethyl glyoxalate and diethyl ketomalonate via electrogenerated superoxide.
Sugawara M and Baizer MM.
Tetrahedron Letters, 24(22), 2223-2226 (1983)
Microwave Enhanced Knoevenagel Condensation of Ethyl Cyanoacetate with Aldehydes.
Kim S-Y, et al.
Synthetic Communications, 27(4), 533-541 (1997)
Yuya Oka et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(39), 9362-9368 (2017-05-18)
Mesoporous basic Mg-Al mixed metal oxides (MMOs) with a high surface area and large pore size have been prepared through the assembly of monodispersed layered double hydroxide nanoparticles (LDHNPs) with block copolymer templates. The particle sizes of the LDHNPs were
Mohie E M Zayed et al.
Journal of fluorescence, 27(3), 853-860 (2017-01-23)
4-(2,3,4-trimethoxyphenyl)-8-methoxy-2-oxo-1,2,5,6 tetrahydrobenzo [h] quinoline-3-carbonitrile (TMTQ) dye was synthesized by one-pot multicomponent reactions (MCRs) of 2,3,4 trimethoxybenzaldehyd, ethyl cyanoacetate, 6-methoxy-1,2,3,4-tetrahydro-naphthalin-1-one and ammonium acetate under microwave irradiation. The structures of the synthesized compound was established by spectroscopic (FT-IR
Korany A Ali et al.
Mini reviews in medicinal chemistry, 18(8), 717-727 (2017-04-27)
In this study, synthesis, molecular docking and anticancer screening of new series of substituted heterocycles with trimethoxy phenyl scaffold as Combretastatin analogues were described. Substituted pyridines were synthesized via the reaction of (E)-3-(dimethylamino)-1-(3,4,5- trimethoxyphenyl)prop-2-en-1-one (2) with active methylene reagents. Substituted
商品
Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
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