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质量水平
方案
95%
表单
liquid
自燃温度
599 °F
折射率
n20/D 1.396 (lit.)
沸点
64-65 °C (lit.)
mp
−131.5-−131 °C (lit.)
密度
0.689 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CCC(=C)CC
InChI
1S/C6H12/c1-4-6(3)5-2/h3-5H2,1-2H3
InChI key
RYKZRKKEYSRDNF-UHFFFAOYSA-N
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Danger
危险声明
危险分类
Flam. Liq. 2 - Skin Sens. 1
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
14.0 °F - closed cup
闪点(°C)
-10 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
新产品
Chemistry (Weinheim an der Bergstrasse, Germany), 27(7), 2513-2522 (2020-11-17)
The first intermolecular early main group metal-alkene complexes were isolated. This was enabled by using highly Lewis acidic Mg centers in the Lewis base-free cations (Me BDI)Mg+ and (tBu BDI)Mg+ with B(C6 F5 )4 - counterions (Me BDI=CH[C(CH3 )N(DIPP)]2
Science (New York, N.Y.), 365(6458), 1138-1143 (2019-09-14)
Terminal copper-nitrenoid complexes have inspired interest in their fundamental bonding structures as well as their putative intermediacy in catalytic nitrene-transfer reactions. Here, we report that aryl azides react with a copper(I) dinitrogen complex bearing a sterically encumbered dipyrrin ligand to
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