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Merck
CN

D90008

Sigma-Aldrich

偶氮二甲酸二乙酯

别名:

DEAD

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About This Item

线性分子式:
C2H5OCON=NCOOC2H5
CAS号:
分子量:
174.15
Beilstein:
908662
EC 号:
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:

形式

liquid

杂质

<3% dichloromethane

折射率

n20/D 1.43 (lit.)

bp

106 °C/13 mmHg (lit.)

密度

1.106 g/mL at 25 °C (lit.)

SMILES字符串

CCOC(=O)\N=N\C(=O)OCC

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

InChI key

FAMRKDQNMBBFBR-BQYQJAHWSA-N

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应用

用于Mitsunobu 和Diels-Alder 反应,以及烯烃的烯丙基胺化的试剂

象形图

Exploding BombExclamation mark

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Expl. 1.1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

235.4 °F

闪点(°C)

113 °C

法规信息

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The Journal of Organic Chemistry, 58, 4979-4979 (1993)
The Journal of Organic Chemistry, 58, 5261-5261 (1993)
F K Brown et al.
Journal of medicinal chemistry, 37(5), 674-688 (1994-03-04)
Systematic modification of the presumed P1 side chain in a series of (carboxyalkyl)amino-based inhibitors of matrix metalloproteinases enabled identification of the 2-(1,3-dihydro-1,3-dioxo-2H-benz[f]isoindol-2-yl)ethyl group as a preferred substituent imparting potent inhibition of the enzymes collagenase and gelatinase. It was subsequently found
Gregory S Watson et al.
Acta biomaterialia, 21, 109-122 (2015-03-17)
Geckos, and specifically their feet, have attracted significant attention in recent times with the focus centred around their remarkable adhesional properties. Little attention however has been dedicated to the other remaining regions of the lizard body. In this paper we
Jetze Visser et al.
Nature communications, 6, 6933-6933 (2015-04-29)
Despite intensive research, hydrogels currently available for tissue repair in the musculoskeletal system are unable to meet the mechanical, as well as the biological, requirements for successful outcomes. Here we reinforce soft hydrogels with highly organized, high-porosity microfibre networks that

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