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Merck
CN

D77001

Sigma-Aldrich

己二腈

99%

别名:

1,6-hexanedinitrile, ADN, 1,4-二氰基丁烷

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About This Item

线性分子式:
NC(CH2)4CN
CAS号:
分子量:
108.14
Beilstein:
1740005
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

3.7 (vs air)

质量水平

蒸汽压

0.01 mmHg ( 40 °C)

方案

99%

表单

liquid

自燃温度

1022 °F

expl. lim.

4.99 %

折射率

n20/D 1.438 (lit.)

沸点

295 °C (lit.)

mp

1-3 °C (lit.)

密度

0.951 g/mL at 25 °C (lit.)

SMILES字符串

N#CCCCCC#N

InChI

1S/C6H8N2/c7-5-3-1-2-4-6-8/h1-4H2

InChI key

BTGRAWJCKBQKAO-UHFFFAOYSA-N

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应用

己二腈是制造尼龙-6,6的关键前体。 它可以进行催化氢化以形成六亚甲基二胺(HMD)。 由于其高阳极和热稳定性,ADN非常有潜力作为高压锂电池中电解质溶液的溶剂。

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

闪点(°F)

325.4 °F - closed cup

闪点(°C)

163 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

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Jian-Jun Dai et al.
ChemSusChem, 5(4), 617-620 (2012-03-24)
Current affairs: Adiponitrile, used to produce nylon 6.6, is prepared from the renewable compound glutamic acid by an electrochemical route, involving electro-oxidative decarboxylation and Kolbe coupling reactions. The new route is an example of the use of glutamic acid as
Inhalation toxicity of adiponitrile in rats.
L W Smith et al.
Toxicology and applied pharmacology, 65(2), 257-263 (1982-09-15)
O L Dashiell et al.
Journal of applied toxicology : JAT, 4(6), 320-325 (1984-12-01)
Nine chemicals, with a range from extremely to slightly toxic, were used to measure the oral LD50 in both fasted (24-h) and non-fasted rats. Each chemical was tested as a solution or suspension in corn oil, responses within 14 days
Raghuraj Rao et al.
Analytica chimica acta, 599(1), 24-35 (2007-09-04)
Multivariate calibration problems often involve the identification of a meaningful subset of variables, from a vast number of variables for better prediction of output variables. A new graph theoretic method based on partial correlations (variable interaction network-VIN) is proposed. Many
Soo-Jin Yeom et al.
The Biochemical journal, 415(3), 401-407 (2008-04-17)
Nitrilase from Rhodococcus rhodochrous ATCC 33278 hydrolyses both aliphatic and aromatic nitriles. Replacing Tyr-142 in the wild-type enzyme with the aromatic amino acid phenylalanine did not alter specificity for either substrate. However, the mutants containing non-polar aliphatic amino acids (alanine

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