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Merck
CN

D77001

Sigma-Aldrich

己二腈

99%

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别名:
1,6-hexanedinitrile, ADN, 1,4-二氰基丁烷
线性分子式:
NC(CH2)4CN
CAS号:
分子量:
108.14
Beilstein:
1740005
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

3.7 (vs air)

质量水平

蒸汽压

0.01 mmHg ( 40 °C)

检测方案

99%

形式

liquid

自燃温度

1022 °F

expl. lim.

4.99 %

折射率

n20/D 1.438 (lit.)

bp

295 °C (lit.)

mp

1-3 °C (lit.)

密度

0.951 g/mL at 25 °C (lit.)

SMILES字符串

N#CCCCCC#N

InChI

1S/C6H8N2/c7-5-3-1-2-4-6-8/h1-4H2

InChI key

BTGRAWJCKBQKAO-UHFFFAOYSA-N

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应用

己二腈是制造尼龙-6,6的关键前体。 它可以进行催化氢化以形成六亚甲基二胺(HMD)。 由于其高阳极和热稳定性,ADN非常有潜力作为高压锂电池中电解质溶液的溶剂。

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation

WGK

WGK 1

闪点(°F)

325.4 °F

闪点(°C)

163 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Gerald L Kennedy
Drug and chemical toxicology, 27(2), 123-131 (2004-06-17)
Adiponitrile (ADN) has moderate acute toxicity with an oral LD50 in rats of 100 to 500 mg/kg and a 4-hr LC50 in rats of 1.71 mg/L (vapor plus aerosol). ADN produced slight eye but no skin irritation in rabbits. Repeated
The catalytic hydrogenation of adiponitrile to hexamethylenediamine over a rhodium/alumina catalyst in a three phase slurry reactor.
Alini S, et al.
J. Mol. Catal. A: Chem., 206(1-2), 363-370 (2003)
J L Moreau et al.
Journal of chromatography. B, Biomedical applications, 656(1), 197-202 (1994-06-03)
A procedure for the assay of nitrile hydratase and amidase activity by high-performance liquid chromatography is described. The method can be used to assay the intermediate compounds resulting from the hydrolysis of adiponitrile into adipic acid, and to determine the
J L Moreau et al.
The Analyst, 116(12), 1381-1383 (1991-12-01)
A procedure for the assay of nitrile hydratase and amidase activities by high-performance liquid chromatography is described. The method can be used to assay the intermediate compounds resulting from the hydrolysis of adiponitrile to adipic acid, and to determine the
O L Dashiell et al.
Journal of applied toxicology : JAT, 4(6), 320-325 (1984-12-01)
Nine chemicals, with a range from extremely to slightly toxic, were used to measure the oral LD50 in both fasted (24-h) and non-fasted rats. Each chemical was tested as a solution or suspension in corn oil, responses within 14 days

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