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Merck
CN

D62403

Sigma-Aldrich

1,2-二氯乙烯,顺反异构体混合物

98%

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别名:
1,2-Dichloroethene, Acetylene dichloride, sym-Dichloroethylene
线性分子式:
ClCH=CHCl
CAS号:
分子量:
96.94
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

5.32 psi ( 20 °C)

质量水平

检测方案

98%

形式

liquid

折射率

n20/D 1.447 (lit.)

bp

48-60 °C (lit.)

mp

−57 °C (lit.)

密度

1.265 g/mL at 25 °C (lit.)

SMILES字符串

Cl\C=C\Cl

InChI

1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+

InChI key

KFUSEUYYWQURPO-OWOJBTEDSA-N

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应用

1,2-二氯乙烯,顺反异构体混合物可作为反应剂:
  • 与末端炔烃经Sonogashira偶联反应合成氯烯炔
  • 在氯化铝的存在下与酰氯经Friedel-Crafts酰化反应合成三氯乙基烷酮
  • 与2-(三丁基锡)噻唑经钯催化的Stille偶联反应合成(乙烯二基)双[噻唑]

象形图

FlameExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Flam. Liq. 2

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

分析证书(COA)

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Jisu Hong et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(2), 649-656 (2018-11-06)
The effects of the molecular structure of thiazole-based polymers on the active layer morphologies and performances of electronic and photovoltaic devices were studied. Thus, thiazole-based conjugated polymers with a novel thiazole-vinylene-thiazole (TzVTz) structure were designed and synthesized. The TzVTz structure
A quantum chemical study of unexpected reaction of alpha-chloroacyl chlorides with 1, 2-dichloroethylene in the presence of aluminum chloride
Shagun V, et al.
Computational & Theoretical Chemistry, 1073, 116-122 (2015)
Timothy E Mattes et al.
FEMS microbiology reviews, 34(4), 445-475 (2010-02-12)
Extensive use and inadequate disposal of chloroethenes have led to prevalent groundwater contamination worldwide. The occurrence of the lesser chlorinated ethenes [i.e. vinyl chloride (VC) and cis-1,2-dichloroethene (cDCE)] in groundwater is primarily a consequence of incomplete anaerobic reductive dechlorination of
Yu-long Liu et al.
Huan jing ke xue= Huanjing kexue, 31(7), 1526-1532 (2010-09-10)
Mixed plumes contained chlorinated solvents and petroleum hydrocarbons which mainly refers to BTEX (benzene, toluene, ethylbenzene and xylenes) in groundwater can be remediated by sequential units combined an iron permeable reactive barrier (Fe0-PRB) with an anoxic wall. In design of
Jaejin Lee et al.
Biodegradation, 22(4), 687-698 (2010-11-06)
Tetrachloroethene (PCE) and trichloroethene (TCE) are common groundwater contaminants that also impact tidal flats, especially near urban and industrial areas. However, very little is known about dechlorinating microbial communities in tidal flats. Titanium pyrosequencing, 16S rRNA gene clone libraries, and

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