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蒸汽密度
4.46 (vs air)
质量水平
蒸汽压
1.9 mmHg ( 20 °C)
方案
≥98%
表单
liquid
自燃温度
594 °F
expl. lim.
10 %
折射率
n20/D 1.417 (lit.)
pH值(酸碱度)
11.1 (20 °C, 1 g/L)
沸点
159 °C (lit.)
mp
−62 °C (lit.)
密度
0.767 g/mL at 25 °C (lit.)
SMILES字符串
CCCCNCCCC
InChI
1S/C8H19N/c1-3-5-7-9-8-6-4-2/h9H,3-8H2,1-2H3
InChI key
JQVDAXLFBXTEQA-UHFFFAOYSA-N
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应用
- 二丁基胺广泛用于钯催化与芳基卤化物交叉偶联合成芳基胺,通称为 Buchwald–Hartwig 胺化。
- 可用于氧杂酮介导的 2-氨基苯甲酰胺和 1,2-二氨基苯的环合反应,分别合成 2,3-二氢喹唑啉-4 (1 H )-酮和 1 H -苯并咪唑。
- 也可用于一锅法多组分反应,合成四取代和五取代的多官能团二氢吡咯。
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
104.9 °F - closed cup
闪点(°C)
40.5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Oxone-mediated annulation of 2-aminobenzamides and 1, 2-diaminobenzenes with sec-amines via imine-N-oxides: new syntheses of 2, 3-dihydroquinazolin-4 (1 H)-ones and 1 H-benzimidazoles.
Sriramoju V, et al.
New. J. Chem., 42(5), 3188-3191 (2018)
Simple, efficient catalyst system for the palladium-catalyzed amination of aryl chlorides, bromides, and triflates.
Wolfe J P, et al.
The Journal of Organic Chemistry, 65(4), 1158-1174 (2000)
Concise and versatile multicomponent synthesis of multisubstituted polyfunctional dihydropyrroles.
Zhu Q, et al.
Journal of Combinatorial Chemistry, 11(4), 685-696 (2009)
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
Kuwano R, et al.
The Journal of Organic Chemistry, 67(18), 6479-6486 (2002)
Baiyi Xue et al.
Journal of mass spectrometry : JMS, 46(7), 689-695 (2011-07-12)
Characterization of glycosaminoglycans poses a challenge for current analytical techniques, as they are highly acidic, polydisperse and heterogeneous compounds. The purpose of this study is the separation and analysis of a partially depolymerized heparin-like glycosaminoglycan by on-line ion-pairing reversed-phase high-performance
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