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Merck
CN

D35457

Sigma-Aldrich

N,N-二苄基羟胺

98%

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线性分子式:
(C6H5CH2)2NOH
CAS号:
分子量:
213.28
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

crystals

mp

125-128 °C (lit.)

SMILES字符串

ON(Cc1ccccc1)Cc2ccccc2

InChI

1S/C14H15NO/c16-15(11-13-7-3-1-4-8-13)12-14-9-5-2-6-10-14/h1-10,16H,11-12H2

InChI key

GXELTROTKVKZBQ-UHFFFAOYSA-N

应用

N,N-Dibenzylhydroxylamine, upon oxidation, yields N-benzyl-α-phenylnitrone, which can undergo cycloaddition reaction with suitable dipolarophiles. It can be used to synthesize N,N,O-trisubstituted hydroxylamines and arylamines.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Synthesis of N,N,O-Trisubstituted Hydroxylamines by Stepwise Reduction and Substitution of O-Acyl N, N-Disubstituted Hydroxylamines.
Dhanju S and Crich D
Organic Letters, 18(8), 1820-1823 (2016)
Mechanistic studies lead to dramatically improved reaction conditions for the Cu-catalyzed asymmetric hydroamination of olefins.
Bandar JS, et al.
Journal of the American Chemical Society, 137(46), 14812-14818 (2015)
Synthesis of Arylamines via Aminium Radicals.
Svejstrup TD, et al.
Angewandte Chemie (International Edition in English), 56(47), 14948-14952 (2017)
Chemoselective Ligation of Peptide Phenyl Esters with N?Terminal Cysteines.
Fang GM, et al.
Chembiochem, 11(8), 1061-1065 (2010)
Recent developments in nitrone chemistry: some novel transformations.
Yang J
Synlett, 23(16), 2293-2297 (2012)

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