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Merck
CN

D210803

Sigma-Aldrich

亚磷酸二苯酯

别名:

NSC 43786, 磷酸二苯酯

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About This Item

线性分子式:
(C6H5O)2P(O)H
CAS号:
分子量:
234.19
Beilstein:
2051909
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

8.1 (vs air)

质量水平

蒸汽压

5 mmHg ( 140 °C)

表单

liquid

杂质

≤15% phenol

折射率

n20/D 1.558 (lit.)

沸点

218-219 °C/26 mmHg (lit.)

mp

12 °C (lit.)

密度

1.223 g/mL at 25 °C (lit.)

SMILES字符串

O=[PH](Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H11O3P/c13-16(14-11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10,16H

InChI key

OGBPILLJZSJJRC-UHFFFAOYSA-N

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应用

反应物涉及:
  • N -苄基芳基酰胺和二-Phα 的合成-氨基甲膦衍生物用作酯类油热氧稳定性添加剂
  • 一锅三组分 Kabachnik 场反应
  • 可见光介导胺的氧化膦酰化反应
  • 含卤代酮的改良不对称 Pudovik 添加剂
  • 与天然 α-氨基酸的串联脱羧酶偶联

象形图

CorrosionExclamation mark

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

348.8 °F - closed cup

闪点(°C)

176 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Jiesheng Xv et al.
Journal of biomaterials science. Polymer edition, 30(5), 398-414 (2019-01-29)
Zwitterionic polymer is a new generation of anti-fouling materials with its good resistance to protein and bacterial adhesion. Constructing the anti-fouling surfaces with zwitterionic polymer has been regarded as an effective approach for improving the biocompatibility and biofunctionality of clinic
Zhenhua Fang et al.
Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie, 85, 160-168 (2016-12-09)
Osteosarcoma is the most common primary malignant bone tumor in the pediatric age group, and chemotherapy directed by targeted nanoparticulate drug delivery system represents a promising approach for osteosarcoma treatment recently. Here, we designed and developed a novel DOX-loaded targeted
Guanglin Zhang et al.
International journal of biological macromolecules, 133, 58-66 (2019-04-15)
Nanoparticle-based pulmonary delivery of protein therapeutics provides a promising approach for improving protein bioavailability to treat either local or systemic diseases, however high-efficient nanocarrier is a great challenge. Here, biomimetic phosphorylcholine-chitosan nanoparticles (PCCs-NPs) taking advantages of both zwitterionic phosphorylcholine and
Ye He et al.
International journal of biological macromolecules, 163, 1738-1746 (2020-09-18)
A zwitterionic phosphoryldiserine (PDS)- chitosan conjugate was synthesized via Atherton-Todd reaction, and its degree of substitution of PDS and structure were characterized by 1H and 31P NMR spectra, ICP, FTIR and XRD. Thermal analysis confirmed that there existed the freezing
Diana Rogacz et al.
Materials (Basel, Switzerland), 12(12) (2019-06-27)
The aim of this work was to evaluate the impact of the thiophene-derived aminophosphonates 1-6 on seedling emergence and growth of monocotyledonous oat (Avena sativa) and dicotyledonous radish (Raphanus sativus L.), and phytotoxicity against three persistent and resistant weeds (Galinsoga

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