D189006
4,N,N-三甲基苯胺
99%
别名:
4-二甲氨基甲苯, N,N-二甲基-对甲苯胺
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关于此项目
线性分子式:
CH3C6H4N(CH3)2
化学文摘社编号:
分子量:
135.21
Beilstein:
774409
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
蒸汽密度
>1 (vs air)
质量水平
方案
99%
表单
liquid
expl. lim.
7 %
折射率
n20/D 1.546 (lit.)
沸点
211 °C (lit.)
90-92 °C/10 mmHg (lit.)
密度
0.937 g/mL at 25 °C (lit.)
SMILES字符串
CN(C)c1ccc(C)cc1
InChI
1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3
InChI key
GYVGXEWAOAAJEU-UHFFFAOYSA-N
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应用
4,N,N-均三甲苯胺是一种叔胺，可以在存在二叔丁基过氧化物的情况下与苯乙炔和苯甲酰胺进行铁催化氧化C-C偶联，分别形成N,4-二甲基-N-（3-苯基丙-2-炔基）苯氮胺和N-（（甲基（对甲苯基）氨基）甲基）苯甲酰胺。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Repr. 2 - Skin Sens. 1 - STOT RE 2 Oral
靶器官
Reproductive organs
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
168.8 °F - closed cup
闪点(°C)
76 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Chemoselective C? H Bond Activation: Ligand and Solvent Free Iron-Catalyzed Oxidative C? C Cross-Coupling of Tertiary Amines with Terminal Alkynes. Reaction Scope and Mechanism.
Volla C M R, et al.
Organic Letters, 11(8), 1701-1704 (2009)
Kyle Winter et al.
Biomaterials, 26(26), 5321-5329 (2005-04-09)
Previous investigations have found that visible-light (VL)-irradiated camphorquinone (CQ), in the presence of a tertiary amine (e.g., N,N-dimethyl-p-toluidine, DMT), generates reactive oxygen species and causes oxidative DNA damage in vitro. In this study, oxidative DNA damage produced by VL-irradiated CQ/DMT
Yi-Ching Li et al.
Journal of biomedical materials research. Part B, Applied biomaterials, 82(1), 23-28 (2006-10-17)
Camphorquinone (CQ) is widely used as an initiator in modern visible-light (VL) cured resin systems. CQ is also characterized as a potential allergenic compound. To date, there is growing concern that CQ may produce genetic damage by inducing mutation. In
Sachiko Kaihara et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 68(1), 67-73 (2007-09-25)
While many synthetic, hydrolytically degradable hydrogels have been developed for biomedical applications, there are only a few examples whose polymer backbone does not form acidic products upon degradation. In order to address this concern, we proposed to develop a hydrogel
Chiemi Hirabayashi et al.
Dental materials journal, 21(4), 314-321 (2003-03-01)
Polymerization characteristics of poly (methyl methacrylate)(PMMA)/(methyl methacrylate) (MMA) resin initiated by tributylborane (TBB) were compared with those by benzoyl peroxide (BPO)/N,N-dimethyl-p-toluidine and camphorquinone (CQ)/N,N-dimethylaminoethyl methacrylate from the aspects of temporal changes of residual MMA and molecular weight up to 4
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