D153303
5,5-二甲基-1,3-环己二酮
95%
别名:
双甲酮, 甲酮
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关于此项目
线性分子式:
(CH3)2C6H6(=O)2
化学文摘社编号:
分子量:
140.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-804-4
Beilstein/REAXYS Number:
471489
MDL number:
Assay:
95%
Form:
powder
InChI key
BADXJIPKFRBFOT-UHFFFAOYSA-N
InChI
1S/C8H12O2/c1-8(2)4-6(9)3-7(10)5-8/h3-5H2,1-2H3
SMILES string
CC1(C)CC(=O)CC(=O)C1
assay
95%
form
powder
Quality Level
mp
146-148 °C (lit.)
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Application
Furannulation 环化策略的一部分，用于合成天然稠合 3-甲基呋喃。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
The Journal of Organic Chemistry, 58, 3960-3960 (1993)
C H Shandrenko et al.
Ukrains'kyi biokhimichnyi zhurnal (1999 ), 83(6), 110-115 (2012-03-01)
A method for endogenous formaldehyde (FA) level evaluation has been worked out. The method involves the administration of dimedone, which forms the stable complex with FA, and the determination of formaldimedone concentration in biological samples by the fluorescence approach. The
Antonio Evidente et al.
Journal of natural products, 74(4), 757-763 (2011-02-24)
Sphaeropsidone and episphaeropsidone are two phytotoxic dimedone methyl ethers produced by Diplodia cupressi, the causal agent of a canker disease of cypress in the Mediterranean area. In this study, eight derivatives obtained by chemical modifications and two natural analogues were
Rebecca N Burns et al.
The Journal of pharmacology and experimental therapeutics, 339(3), 914-921 (2011-09-16)
Reactive oxygen species (ROS), including hydrogen peroxide (H(2)O(2)), have recently been shown to be generated upon agonism of several members of the G protein-coupled receptor (GPCR) superfamily, including β(2)-adrenergic receptors (β(2)ARs). Previously, we have demonstrated that inhibition of intracellular ROS
Candice E Paulsen et al.
Chemistry & biology, 16(2), 217-225 (2009-02-24)
Saccharomyces cerevisiae responds to elevated levels of hydrogen peroxide in its environment via a redox relay system comprising the thiol peroxidase Gpx3 and transcription factor Yap1. In this signaling pathway, a central unresolved question is whether cysteine sulfenic acid modification
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